Reaction Process of WC Prepared under a CO Atmosphere in a Fluidized Bed
文献类型：期刊论文
| 作者 | Pan, Feng4 ; Liu, Jiayi3,4; Du, Zhan4; Zhu, Qingshan1,4; Zhang, Meiju4; Yan, Dong4; Li, Shaofu2,4
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| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2021-01-13 |
| 卷号 | 60期号:1页码:162-172 |
| ISSN号 | 0888-5885 |
| DOI | 10.1021/acs.iecr.0c04003 |
| 英文摘要 | Combined with thermodynamic analysis and various characterizations, such as X-ray diffraction, X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and so on, the reaction process of WC prepared from WO2.72 in a fluidized bed has been investigated under a CO atmosphere in the range of 800-1000 degrees C. The phase analysis results indicate that WO2.72 undergoes different reaction paths to form tungsten carbide in different temperature ranges. Especially, when the reaction temperature is in the range of 900-950 degrees C, the reaction process follows the following reaction route: WO2.72 -> WO2 -> W2C -> WC, while no W2C is produced in the reported literatures. XPS and TEM results show that solid carbon can be formed by the decomposition of carbon monoxide in both high- and low-temperature regions. The reaction process from WO2.72 to WO2 or W mainly depends on the gas-solid heterogeneous reaction in the initial stage. In the deep reduction or carbonization stage, both gas-solid heterogeneous reaction and solid-phase homogeneous reaction are included in the lower temperature region, while the formation of WC mainly depends on the homogeneous reaction between solid carbon and metallic tungsten in the higher temperature region. |
| WOS关键词 | TUNGSTEN CARBIDE POWDERS ; AMMONIUM PARATUNGSTATE ; CATALYTIC ACTIVITY ; CARBURIZATION ; REDUCTION ; MIXTURES ; MECHANISM ; NANOPOWDERS ; DEPOSITION ; WO3 |
| 资助项目 | National Natural Science Foundation of China[21878305] ; National Natural Science Foundation of China[22078326] ; National Natural Science Foundation of China[21908227] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000611072000011 |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/43520]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Pan, Feng; Zhu, Qingshan |
| 作者单位 | 1.Univ Chinese Acad Sci, Coll Chem Engn, Beijing 100049, Peoples R China 2.Nanjing IPE Inst Green Mfg Ind, Nanjing 211135, Peoples R China 3.Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300350, Peoples R China 4.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pan, Feng,Liu, Jiayi,Du, Zhan,et al. Reaction Process of WC Prepared under a CO Atmosphere in a Fluidized Bed[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2021,60(1):162-172. |
| APA | Pan, Feng.,Liu, Jiayi.,Du, Zhan.,Zhu, Qingshan.,Zhang, Meiju.,...&Li, Shaofu.(2021).Reaction Process of WC Prepared under a CO Atmosphere in a Fluidized Bed.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,60(1),162-172. |
| MLA | Pan, Feng,et al."Reaction Process of WC Prepared under a CO Atmosphere in a Fluidized Bed".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 60.1(2021):162-172. |
入库方式： OAI收割
来源：过程工程研究所
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