Dehydrative Formation of Isosorbide from Sorbitol over Poly(ionic liquid)-Covalent Organic Framework Hybrids
文献类型：期刊论文
| 作者 | Du, Yi-Ran1,2; Xu, Bao-Hua1,2; Xia, Shi-Ping1,3; Ding, Guang-Rong1,2; Zhang, Suo-Jiang1,2 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2021-01-13 |
| 卷号 | 13期号:1页码:552-562 |
| 关键词 | poly(ionic liquid)s covalent organic frameworks dehydration sorbitol isosorbide |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/acsami.0c18105 |
| 英文摘要 | In this study, the covalent bonding of linear poly(ionic liquids (PILs) with covalent organic frameworks (COFs) was accessed by copolymerization of a vinyl-decorated COF with 4-vinylbenzyl chloride, followed by quaternization with tertiary amines. The resultant PIL-COF composite by anchoring a proper content of vinyl sites on the COF-based comonomer retains the crystallinity and porosity, thereby facilitating access of the reactants to the catalytic active sites. As a proof of concept, the dehydrative transformation of sorbitol into isosorbide was selected as a benchmark reaction, whose rate improved significantly in the presence of PIL-COF-0.33 compared with those of individual components and the mesoporous PIL counterpart due to uniform pore sizes and flexible linear catalytic chains. In addition, the hybrids bearing a chemical cross-linkage between PILs and COFs are robust, and PIL-COF-0.33 can be recovered and reused for 10 runs without significant reactivity loss. These findings provide the basis for a novel design concept for achieving both efficient and stable IL catalysis. |
| WOS关键词 | IONIC LIQUID ; EFFICIENT ; CO2 ; CYCLOADDITION ; CATALYST |
| 资助项目 | National Natural Science Foundation of China[U1704251] ; Key Research Program of Frontier Sciences, CAS[ZDBS-LY-JSC022] ; Major Program of National Natural Science Foundation of China[21890760] ; Zhengzhou High Level Talent Certificate[20180200052] ; K. C. Wong Education Foundation[GJTD-2018-04] |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000611066000050 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Natural Science Foundation of China ; Key Research Program of Frontier Sciences, CAS ; Major Program of National Natural Science Foundation of China ; Zhengzhou High Level Talent Certificate ; K. C. Wong Education Foundation |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/43630]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Xu, Bao-Hua; Zhang, Suo-Jiang |
| 作者单位 | 1.Chinese Acad Sci, Innovat Acad Green Manufacture, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China 3.East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China |
| 推荐引用方式 GB/T 7714 | Du, Yi-Ran,Xu, Bao-Hua,Xia, Shi-Ping,et al. Dehydrative Formation of Isosorbide from Sorbitol over Poly(ionic liquid)-Covalent Organic Framework Hybrids[J]. ACS APPLIED MATERIALS & INTERFACES,2021,13(1):552-562. |
| APA | Du, Yi-Ran,Xu, Bao-Hua,Xia, Shi-Ping,Ding, Guang-Rong,&Zhang, Suo-Jiang.(2021).Dehydrative Formation of Isosorbide from Sorbitol over Poly(ionic liquid)-Covalent Organic Framework Hybrids.ACS APPLIED MATERIALS & INTERFACES,13(1),552-562. |
| MLA | Du, Yi-Ran,et al."Dehydrative Formation of Isosorbide from Sorbitol over Poly(ionic liquid)-Covalent Organic Framework Hybrids".ACS APPLIED MATERIALS & INTERFACES 13.1(2021):552-562. |
入库方式： OAI收割
来源：过程工程研究所
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