Chlorogallate（Ⅲ） ionic liquids： Synthesis, acidity determination and their catalytic performances for isobutane alkylation
文献类型：期刊论文
| 作者 | Xing Xueqi1; Zhao Guoying1; Cui Jianzhong2 |
| 刊名 | 中国科学：化学英文版
 |
| 出版日期 | 2012 |
| 卷号 | 55.0期号:008页码:1542 |
| 关键词 | 酸性离子液体 烷基化反应 异丁烷 催化性能 酸度测定 合成 催化活性 三乙基 |
| ISSN号 | 1674-7291 |
| 英文摘要 | A series of triethylammonium-based chlorogallate（Ⅲ） ionic liquids with varied Lewis acidity was synthesized, characterized, and firstly applied to isobutane alkylation. The Et3NHC1-GaCl3 with XGaCl3 =0.65 displayed a potential catalytic activity for the alkylation. The addition of copper halide into the chlorogallate（Ⅲ） ionic liquids dramatically enhanced the alkylation reac- tion. Up to 70.1% Cs selectivity and 91.3 RON were achieved with the Et3NHC1-GaC13-CuC1 （XGaCl3 = 0.65, CuCI = 5% tool） under 0.5 MPa, 900 r/min, 15 min, 288 K using the industrial C4 cut （isobutane/butene = 10）. These results indicate that the chlorogallate（Ⅲ） system may be used as a promising catalyst for the C4 alkylation. |
| 语种 | 英语 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/44443]  |
| 专题 | 中国科学院过程工程研究所 |
| 作者单位 | 1.中国科学院过程工程研究所 2.天津大学 |
| 推荐引用方式 GB/T 7714 | Xing Xueqi,Zhao Guoying,Cui Jianzhong. Chlorogallate（Ⅲ） ionic liquids： Synthesis, acidity determination and their catalytic performances for isobutane alkylation[J]. 中国科学：化学英文版,2012,55.0(008):1542. |
| APA | Xing Xueqi,Zhao Guoying,&Cui Jianzhong.(2012).Chlorogallate（Ⅲ） ionic liquids： Synthesis, acidity determination and their catalytic performances for isobutane alkylation.中国科学：化学英文版,55.0(008),1542. |
| MLA | Xing Xueqi,et al."Chlorogallate（Ⅲ） ionic liquids： Synthesis, acidity determination and their catalytic performances for isobutane alkylation".中国科学：化学英文版 55.0.008(2012):1542. |
入库方式： OAI收割
来源：过程工程研究所
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