Isobaric vapor–liquid equilibrium for binary system of aniline + methyl-N-phenyl carbamate
文献类型：期刊论文
| 作者 | Li Yuqian2; Wang Liguo3; He Peng3; Huang Kelin1; Li Huiquan3; Cao Yan3 |
| 刊名 | Chinese Journal of Chemical Engineering
 |
| 出版日期 | 2016 |
| 卷号 | 24期号:10页码:1470 |
| 关键词 | Vapor–liquid equilibrium Aniline NRTL Wilson |
| ISSN号 | 1004-9541 |
| 英文摘要 | In this study, the quasi-static ebulliometric method was used to measure both of the vapor pressures of methyl N -phenyl carbamate (MPC), and the isobaric vapor–liquid equilibrium (VLE) data of the aniline and MPC binary system. The measured vapor pressure data of MPC, at different temperature ranging from 369.60 to 389.54 K, fitted well with the Antoine equation. The VLE data for the aniline and MPC system at (2.00, 4.00, 6.00, 7.00 and 8.00) kPa were correlated by both of nonrandom two-liquid (NRTL) and Wilson models. The parameters of the two models were obtained by regressing the experimental data, with the absolute temperature deviations of 0.54 K and 0.53 K, respectively. The relative volatility of the binary system calculated was all far more than 1, which gives the conclusion that the high purity MPC can be separated from aniline and MPC binary system by rectification or distillation technology. |
| 语种 | 英语 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/47276]  |
| 专题 | 中国科学院过程工程研究所 |
| 作者单位 | 1.China Academy of Science & Technology Development, Guangxi Branch 2.Chemistry and Material Science College, Guangxi Teacher Education University 3.中国科学院过程工程研究所 |
| 推荐引用方式 GB/T 7714 | Li Yuqian,Wang Liguo,He Peng,et al. Isobaric vapor–liquid equilibrium for binary system of aniline + methyl-N-phenyl carbamate[J]. Chinese Journal of Chemical Engineering,2016,24(10):1470. |
| APA | Li Yuqian,Wang Liguo,He Peng,Huang Kelin,Li Huiquan,&Cao Yan.(2016).Isobaric vapor–liquid equilibrium for binary system of aniline + methyl-N-phenyl carbamate.Chinese Journal of Chemical Engineering,24(10),1470. |
| MLA | Li Yuqian,et al."Isobaric vapor–liquid equilibrium for binary system of aniline + methyl-N-phenyl carbamate".Chinese Journal of Chemical Engineering 24.10(2016):1470. |
入库方式： OAI收割
来源：过程工程研究所
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