中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synergistic effect for co-coking of sawdust and coal blending based on the chemical structure transformation

文献类型:期刊论文

作者Qin, Linbo1,2,3; Han, Jun1,3; Zhao, Bo1,3; Chen, Wangsheng1,3; Wan, Yong2
刊名JOURNAL OF THE ENERGY INSTITUTE
出版日期2020-12-01
卷号93期号:6页码:2215-2227
关键词Sawdust Coal blending Co-coking Chemical structure Synergistic effect In-situ FTIR-MS
ISSN号1743-9671
DOI10.1016/j.joei.2020.06.003
英文摘要Biomass was used as additives in coal blending for making coke in terms of widening the alternative raw materials and reducing CO2 emissions. To obtain the influences of biomass incorporation on the semicoke formation, the chemical structure transformation as well as the gas evolution during sawdust (SD)/coal blending (BC) co-coking were investigated using in-situ Fourier transform infrared spectroscopy coupled with mass spectrometry (In-situ FTIR-MS). Meanwhile, the role of biomass in the semicoke formation was also characterized by several analytical techniques. The transformation of the five main functional groups between SD and BC exhibited the largest difference, and the synergistic effect based on the chemical structure transformation was also proposed for the SD/BC blends co-coking. The synergistic effect based on the chemical structure transformation was divided into two stages during semicoke formation. One stage occurred at 100-280 degrees C that was assigned to the physical effect that inhibited the BC decomposition. Another stage happened at 280-500 degrees C that was mainly attributed to the hydrogen transfer that enhanced the aromatization of semi-coke. In addition, it was also noted that the thermo-plastic properties decreased proportionately to the quantity of the SD, and the non-agglomeration between BC and SD was clearly observed by SEM. (C) 2020 Energy Institute. Published by Elsevier Ltd. All rights reserved.
资助项目National Natural Science Foundation of China[51706160] ; Hubei Technological Innovation Special Fund[2019ACA157] ; Hubei Technological Innovation Special Fund[2019AHB073] ; Hubei Technological Innovation Special Fund[2019ZYYD060] ; Foundation for Outstanding Youth Innovative Research Groups of Higher Education Institution in Hubei Province[T201902]
WOS研究方向Energy & Fuels
语种英语
WOS记录号WOS:000590678000008
出版者ELSEVIER SCI LTD
源URL[http://119.78.100.198/handle/2S6PX9GI/25251]  
专题中科院武汉岩土力学所
通讯作者Qin, Linbo; Han, Jun; Wan, Yong
作者单位1.Wuhan Univ Sci & Technol, Hubei Prov Ind Safety Engn Technol Res Ctr, Wuhan 430081, Peoples R China
2.Chinese Acad Sci, Inst Rock & Soil Mech, State Key Lab Geomech & Geotech Engn, Wuhan 430071, Peoples R China
3.Wuhan Univ Sci & Technol, Hubei Key Lab Efficient Utilizat & Agglomerat Met, Wuhan 430081, Peoples R China
推荐引用方式
GB/T 7714
Qin, Linbo,Han, Jun,Zhao, Bo,et al. Synergistic effect for co-coking of sawdust and coal blending based on the chemical structure transformation[J]. JOURNAL OF THE ENERGY INSTITUTE,2020,93(6):2215-2227.
APA Qin, Linbo,Han, Jun,Zhao, Bo,Chen, Wangsheng,&Wan, Yong.(2020).Synergistic effect for co-coking of sawdust and coal blending based on the chemical structure transformation.JOURNAL OF THE ENERGY INSTITUTE,93(6),2215-2227.
MLA Qin, Linbo,et al."Synergistic effect for co-coking of sawdust and coal blending based on the chemical structure transformation".JOURNAL OF THE ENERGY INSTITUTE 93.6(2020):2215-2227.

入库方式: OAI收割

来源:武汉岩土力学研究所

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