MOF-derived NiCoZnP nanoclusters anchored on hierarchical N-doped carbon nanosheets array as bifunctional electrocatalysts for overall water splitting
文献类型：期刊论文
| 作者 | Chen, Bin1,2,3,4; Kim, Dokyoung3; Zhang, Zhuo3; Lee, Minseok3; Yong, Kijung3 |
| 刊名 | CHEMICAL ENGINEERING JOURNAL
 |
| 出版日期 | 2021-10-15 |
| 卷号 | 422 |
| ISSN号 | 1385-8947 |
| 关键词 | Bifunctional electrocatalysts Transition metal phosphide N-doped carbon Metal-organic frameworks Overall water splitting |
| DOI | 10.1016/j.cej.2021.130533 |
| 通讯作者 | Yong, Kijung(kyong@postech.ac.kr) |
| 英文摘要 | The development of novel bifunctional electrocatalysts for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is urgently desired for improving the efficiency of overall water splitting but remains a great challenge. Herein, a metal-organic frameworks (MOFs)-derived hybrid nanostructure consisted of multiple transition metal phosphide (NiCoZnP) nanoclusters and hierarchical ultrathin N-doped carbon (NC) nanosheets is successfully synthesized as binder-free bifunctional electrocatalysts for overall water splitting. The ultrafine and monodispersed NiCoZnP nanoclusters with uniform sizes of 3 nm are homogeneously distributed on the ultrathin NC nanosheets, leading to self-supported NiCoZnP/NC nanosheets array on carbon cloth (CC). The NiCoZnP/NC exhibits large surface area and numerous active sites due to the small sizes of NiCoZnP and hierarchical nanostructures of NC. Furthermore, the NiCoZnP/NC nanosheets are directly grown on CC and avoids the usage of binder, which significantly reduces the electrical contact resistance and exhibits superhydrophilic performance. Therefore, the self-supported NiCoZnP/NC nanosheets array demonstrates high HER activity with low overpotential of 74 mV and OER activity with overpotential of 228 mV to reach current density of 10 mA cm-2 in 1.0 M KOH solution, and exhibits remarkable overall water splitting performances with low potential of 1.54 V to drive 10 mA cm-2 and good long-term stability. |
| WOS关键词 | METAL-ORGANIC FRAMEWORKS ; EFFICIENT ELECTROCATALYSTS ; EVOLUTION REACTION ; HIGHLY EFFICIENT ; OXYGEN ; FABRICATION ; CATALYST |
| 资助项目 | National Research Foundation of Korea[NRF-2019R1A2C2002156] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCIENCE SA |
| WOS记录号 | WOS:000672588900003 |
| 资助机构 | National Research Foundation of Korea |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/123547]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Yong, Kijung |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Mat Phys, Hefei 230031, Peoples R China 2.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China 3.Pohang Univ Sci & Technol POSTECH, Dept Chem Engn, Surface Chem Lab Elect Mat, Pohang 37673, South Korea 4.Chinese Acad Sci, Anhui Key Lab Nanomat & Nanotechnol, Inst Solid State Phys, HFIPS, Hefei 230031, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Bin,Kim, Dokyoung,Zhang, Zhuo,et al. MOF-derived NiCoZnP nanoclusters anchored on hierarchical N-doped carbon nanosheets array as bifunctional electrocatalysts for overall water splitting[J]. CHEMICAL ENGINEERING JOURNAL,2021,422. |
| APA | Chen, Bin,Kim, Dokyoung,Zhang, Zhuo,Lee, Minseok,&Yong, Kijung.(2021).MOF-derived NiCoZnP nanoclusters anchored on hierarchical N-doped carbon nanosheets array as bifunctional electrocatalysts for overall water splitting.CHEMICAL ENGINEERING JOURNAL,422. |
| MLA | Chen, Bin,et al."MOF-derived NiCoZnP nanoclusters anchored on hierarchical N-doped carbon nanosheets array as bifunctional electrocatalysts for overall water splitting".CHEMICAL ENGINEERING JOURNAL 422(2021). |
入库方式： OAI收割
来源：合肥物质科学研究院
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