In Situ Growth of Ultrathin Ni(OH)(2) Nanosheets as Catalyst for Electrocatalytic Oxidation Reactions
文献类型：期刊论文
| 作者 | Zhang, Jifang1,3; Gong, Wanbing1; Yin, Huajie1,2; Wang, Dongdong1,3; Zhang, Yunxia1 ; Zhang, Haimin1; Wang, Guozhong1; Zhao, Huijun1,2
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| 刊名 | CHEMSUSCHEM
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| 出版日期 | 2021-06-09 |
| 关键词 | biomass valorization electrocatalysis 5-hydroxymethylfurfural nickel oxidation |
| ISSN号 | 1864-5631 |
| DOI | 10.1002/cssc.202100811 |
| 通讯作者 | Gong, Wanbing(wbgong@issp.ac.cn) ; Zhao, Huijun(h.zhao@griffith.edu.au) |
| 英文摘要 | Development of electrocatalysts that are capable of efficiently oxidizing biomass-derived 5-hydroxymethylfurfural (HMF) into 2,5-furandicarboxylic acid (FDCA) is critically important for production of degradable plastics via non-fossil routes. In this study, a facile and scalable immersion synthetic approach has been developed to grow ultrathin nickel hydroxide nanosheets in situ on commercial nickel foam (Ni(OH)(2)/NF) as an anode for the electrocatalytic oxidation of HMF to FDCA with complete HMF conversion, 100 % FDCA yield, and >99 % faradaic efficiency at 1.39 V (vs. RHE) within 90 min. Mechanistic studies reveal that the initial oxidation of HMF takes place at the carbonyl group and FDCA is generated through two further oxidation steps. Impressively, the synthesized Ni(OH)(2)/NF can also be used to electrocatalytically oxidize other alcohol/aldehyde-containing compounds to the targeted products in alkaline medium with 100 % yield and >94 % faradaic efficiency under a low oxidation potential of 1.39 V (vs. RHE) within short reaction times. |
| WOS关键词 | ELECTROCHEMICAL OXIDATION ; OXYGEN EVOLUTION ; 2,5-FURANDICARBOXYLIC ACID ; HYDROGEN-PRODUCTION ; EFFICIENT ; WATER |
| 资助项目 | National Natural Science Foundation of China[51902311] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics |
| 语种 | 英语 |
| WOS记录号 | WOS:000659413500001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/123722]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Gong, Wanbing; Zhao, Huijun |
| 作者单位 | 1.Chinese Acad Sci, CAS Ctr Excellence Nanosci,Inst Solid State Phys, Ctr Environm & Energy Nanomat,HFIPS, Anhui Key Lab Nanomat & Nanotechnol,Key Lab Mat P, Hefei 230031, Peoples R China 2.Griffith Univ, Ctr Clean Environm & Energy, Gold Coast Campus, Gold Coast, Qld 4222, Australia 3.Univ Sci & Technol China, Hefei 230026, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Jifang,Gong, Wanbing,Yin, Huajie,et al. In Situ Growth of Ultrathin Ni(OH)(2) Nanosheets as Catalyst for Electrocatalytic Oxidation Reactions[J]. CHEMSUSCHEM,2021. |
| APA | Zhang, Jifang.,Gong, Wanbing.,Yin, Huajie.,Wang, Dongdong.,Zhang, Yunxia.,...&Zhao, Huijun.(2021).In Situ Growth of Ultrathin Ni(OH)(2) Nanosheets as Catalyst for Electrocatalytic Oxidation Reactions.CHEMSUSCHEM. |
| MLA | Zhang, Jifang,et al."In Situ Growth of Ultrathin Ni(OH)(2) Nanosheets as Catalyst for Electrocatalytic Oxidation Reactions".CHEMSUSCHEM (2021). |
入库方式： OAI收割
来源：合肥物质科学研究院
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