Ethanol-extraction SERS strategy for highly sensitive detection of poisons in oily matrix
文献类型:期刊论文
作者 | Wang, Yongtao2,4; Li, Pan2; Lin, Dongyue2; Chen, Jianyi3; Zhang, Yunfeng1; Yang, Liangbao2 |
刊名 | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY |
出版日期 | 2021-10-05 |
卷号 | 259 |
ISSN号 | 1386-1425 |
关键词 | Surface-enhanced Raman spectroscopy Au NRs Solvent extraction Paraquat Diquat Sensitive detection |
DOI | 10.1016/j.saa.2021.119883 |
通讯作者 | Li, Pan(lipan2011@iim.ac.cn) ; Lin, Dongyue(dylin@iim.ac.cn) ; Yang, Liangbao(lbyang@iim.ac.cn) |
英文摘要 | The sensitive detection and identification of toxicants in oily matrices have suffered from difficulty in poi-soning incidents, therefore it is necessary to develop the rapid and efficient analytical method to realize the on-site screening and analyzing. In this report, the surface-enhanced Raman spectroscopy (SERS) method was used to detect paraquat and diquat poisons in various oily matrix coupled with solvent extraction. The solvent extraction not only remove interfering impurities of oily substrates, but also can enrich and separate the poisons from oily matrix. It was demonstrated that the ethanol as the extrac-tant was suitable for the rapid separation of poisons such as paraquat (PQ) and diquat (DQ) in oily matrix (soy sauce, pasta sauce, sesame oil, chili oil). Moreover, combined with a handheld Raman spectrometer, the entire detection process was completed within 8 min with the level of 10 ppb PQ and 100 ppb DQ. Furthermore, double-blind experiments verify the reliability of this method. The results demonstrate that this rapid and convenient method could be used for the effective enrichment and sensitive detection of poisons in several oily matrix and has the grate potential application in emergency response and public safety. (c) 2021 Elsevier B.V. All rights reserved. |
WOS关键词 | LIQUID-CHROMATOGRAPHY ; PARAQUAT ; RAMAN ; DIQUAT ; PLASMA ; URINE ; SUBSTRATE |
资助项目 | National Science Foundation of China[61605221] ; National Science Foundation of China[21974142] ; Opening Foundation of Beijing onsite material evidence testing engineering technology research center[2020CSEEKFKT07] ; Scitech Police Project of Anhui Province[201904d07020009] ; Scitech Police Project of Anhui Province[1804d08020308] |
WOS研究方向 | Spectroscopy |
语种 | 英语 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
WOS记录号 | WOS:000663534100012 |
资助机构 | National Science Foundation of China ; Opening Foundation of Beijing onsite material evidence testing engineering technology research center ; Scitech Police Project of Anhui Province |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/123881] |
专题 | 中国科学院合肥物质科学研究院 |
通讯作者 | Li, Pan; Lin, Dongyue; Yang, Liangbao |
作者单位 | 1.Minist Publ Secur, Inst Forens Sci, Beijing 100038, Peoples R China 2.Chinese Acad Sci, Hefei Inst Phys Sci, Inst Hlth & Med Technol, Hefei 230031, Peoples R China 3.Hefei Eight Senior High Sch, Hefei 230071, Peoples R China 4.Univ Sci & Technol China, Hefei 230026, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Yongtao,Li, Pan,Lin, Dongyue,et al. Ethanol-extraction SERS strategy for highly sensitive detection of poisons in oily matrix[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2021,259. |
APA | Wang, Yongtao,Li, Pan,Lin, Dongyue,Chen, Jianyi,Zhang, Yunfeng,&Yang, Liangbao.(2021).Ethanol-extraction SERS strategy for highly sensitive detection of poisons in oily matrix.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,259. |
MLA | Wang, Yongtao,et al."Ethanol-extraction SERS strategy for highly sensitive detection of poisons in oily matrix".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 259(2021). |
入库方式: OAI收割
来源:合肥物质科学研究院
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。