中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Ethanol-extraction SERS strategy for highly sensitive detection of poisons in oily matrix

文献类型:期刊论文

作者Wang, Yongtao2,4; Li, Pan2; Lin, Dongyue2; Chen, Jianyi3; Zhang, Yunfeng1; Yang, Liangbao2
刊名SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
出版日期2021-10-05
卷号259
ISSN号1386-1425
关键词Surface-enhanced Raman spectroscopy Au NRs Solvent extraction Paraquat Diquat Sensitive detection
DOI10.1016/j.saa.2021.119883
通讯作者Li, Pan(lipan2011@iim.ac.cn) ; Lin, Dongyue(dylin@iim.ac.cn) ; Yang, Liangbao(lbyang@iim.ac.cn)
英文摘要The sensitive detection and identification of toxicants in oily matrices have suffered from difficulty in poi-soning incidents, therefore it is necessary to develop the rapid and efficient analytical method to realize the on-site screening and analyzing. In this report, the surface-enhanced Raman spectroscopy (SERS) method was used to detect paraquat and diquat poisons in various oily matrix coupled with solvent extraction. The solvent extraction not only remove interfering impurities of oily substrates, but also can enrich and separate the poisons from oily matrix. It was demonstrated that the ethanol as the extrac-tant was suitable for the rapid separation of poisons such as paraquat (PQ) and diquat (DQ) in oily matrix (soy sauce, pasta sauce, sesame oil, chili oil). Moreover, combined with a handheld Raman spectrometer, the entire detection process was completed within 8 min with the level of 10 ppb PQ and 100 ppb DQ. Furthermore, double-blind experiments verify the reliability of this method. The results demonstrate that this rapid and convenient method could be used for the effective enrichment and sensitive detection of poisons in several oily matrix and has the grate potential application in emergency response and public safety. (c) 2021 Elsevier B.V. All rights reserved.
WOS关键词LIQUID-CHROMATOGRAPHY ; PARAQUAT ; RAMAN ; DIQUAT ; PLASMA ; URINE ; SUBSTRATE
资助项目National Science Foundation of China[61605221] ; National Science Foundation of China[21974142] ; Opening Foundation of Beijing onsite material evidence testing engineering technology research center[2020CSEEKFKT07] ; Scitech Police Project of Anhui Province[201904d07020009] ; Scitech Police Project of Anhui Province[1804d08020308]
WOS研究方向Spectroscopy
语种英语
出版者PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号WOS:000663534100012
资助机构National Science Foundation of China ; Opening Foundation of Beijing onsite material evidence testing engineering technology research center ; Scitech Police Project of Anhui Province
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/123881]  
专题中国科学院合肥物质科学研究院
通讯作者Li, Pan; Lin, Dongyue; Yang, Liangbao
作者单位1.Minist Publ Secur, Inst Forens Sci, Beijing 100038, Peoples R China
2.Chinese Acad Sci, Hefei Inst Phys Sci, Inst Hlth & Med Technol, Hefei 230031, Peoples R China
3.Hefei Eight Senior High Sch, Hefei 230071, Peoples R China
4.Univ Sci & Technol China, Hefei 230026, Peoples R China
推荐引用方式
GB/T 7714
Wang, Yongtao,Li, Pan,Lin, Dongyue,et al. Ethanol-extraction SERS strategy for highly sensitive detection of poisons in oily matrix[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2021,259.
APA Wang, Yongtao,Li, Pan,Lin, Dongyue,Chen, Jianyi,Zhang, Yunfeng,&Yang, Liangbao.(2021).Ethanol-extraction SERS strategy for highly sensitive detection of poisons in oily matrix.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,259.
MLA Wang, Yongtao,et al."Ethanol-extraction SERS strategy for highly sensitive detection of poisons in oily matrix".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 259(2021).

入库方式: OAI收割

来源:合肥物质科学研究院

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