Catalytic water oxidation by an in situ generated ruthenium nitrosyl complex bearing a bipyridine-bis(atkoxide) ligand
文献类型：期刊论文
| 作者 | Liu, Yingying1; Ng, Siu-Mui2; Yiu, Shek-Man3; Lau, Tai-Chu3 |
| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2021-07-31 |
| ISSN号 | 1477-9226 |
| DOI | 10.1039/d1dt01918j |
| 通讯作者 | Liu, Yingying(yyliu@iim.ac.cn) ; Lau, Tai-Chu(bhiclau@cityu.edu.hk) |
| 英文摘要 | Oxidative degradation and transformation of catalysts are commonly observed in water oxidation by molecular catalysts, especially when a highly oxidizing reagent such as (NH4)(2)[Ce(NO3)(6)] [Ce(IV)] is used. We report herein the synthesis of a ruthenium(m) complex bearing an oxidative resistant bipyridine-bis(alk-oxide) ligand, (Ru(bdalk)(pic)(2)](+) (1, H(2)bdalk = 2,2'-([2,2'-bipyridine]-6,6'-diyl)bis(propan-2-ol), pic = 4-picoline) as a water oxidation catalyst (WOC). A ruthenium(s) nitrosyl complex [Ru(Hbdalk)(NO)(pic)(2)](2+) (3) was also formed during the water oxidation process by 1/Ce(IV), and was isolated and structurally characterized. Complex 3 was found to be an active WOC, with the nitrosyl group remaining intact during water oxidation. |
| WOS关键词 | REDOX PROPERTIES ; HIGHLY EFFICIENT ; INTERMEDIATE ; EVOLUTION |
| 资助项目 | National Natural Science Foundation of China[22001253] ; Research Grants Council of Hong Kong[CityU 11301618] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000686620700001 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | National Natural Science Foundation of China ; Research Grants Council of Hong Kong |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/124447]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Liu, Yingying; Lau, Tai-Chu |
| 作者单位 | 1.Chinese Acad Sci, Inst Intelligent Machines, Hefei Inst Phys Sci, Hefei 230031, Peoples R China 2.Technol & Higher Educ Inst Hong Kong THEi, Dept Food & Hlth Sci, 20A Tsing Yi Rd, Hong Kong, Peoples R China 3.City Univ Hong Kong, Dept Chem, Kowloon Tong, Tat Chee Ave, Hong Kong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Yingying,Ng, Siu-Mui,Yiu, Shek-Man,et al. Catalytic water oxidation by an in situ generated ruthenium nitrosyl complex bearing a bipyridine-bis(atkoxide) ligand[J]. DALTON TRANSACTIONS,2021. |
| APA | Liu, Yingying,Ng, Siu-Mui,Yiu, Shek-Man,&Lau, Tai-Chu.(2021).Catalytic water oxidation by an in situ generated ruthenium nitrosyl complex bearing a bipyridine-bis(atkoxide) ligand.DALTON TRANSACTIONS. |
| MLA | Liu, Yingying,et al."Catalytic water oxidation by an in situ generated ruthenium nitrosyl complex bearing a bipyridine-bis(atkoxide) ligand".DALTON TRANSACTIONS (2021). |
入库方式： OAI收割
来源：合肥物质科学研究院
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