中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
首页 机构 成果 学者
  
  1. CAS IR Grid
  2. 烟台海岸带研究所
  3. 中国科学院烟台海岸带研究所
  4. 中科院海岸带环境过程与生态修复重点实验室
Translating potentiometric detection into non-enzymatic amperometric measurement of H2O2

文献类型：期刊论文

作者Yin, Tanji1,2,4,5; Wang, Hemin3,4,5; Li, Jinghui1,2,4,5; Yuan, Baiqing3; Qin, Wei1,2,4,5
刊名TALANTA
出版日期2021-09-01
卷号232页码:7
关键词Ion-selective electrodes Amperometric readout H2O2 Ca2+ NO3-
ISSN号0039-9140
DOI10.1016/j.talanta.2021.122489
通讯作者Yin, Tanji(tjyin@yic.ac.cn) ; Yuan, Baiqing(bqyuan@ldu.edu.cn)
英文摘要The developments of alternative signal readout strategies for the ion-selective electrodes (ISEs) are necessary in order to break through the limitation of the Nernst equation. In this work, a simple, convenient and easily operated strategy based on the non-enzymatic amperometric measurement of H2O2 is proposed to read out the potentiometric responses for the ISEs. The proposed amperometric signal readout based on H2O2 is carried out in a two compartment electrochemical cell configuration containing a detection cell and a sample cell, physically connected by a salt bridge. A glassy carbon (GC) electrode is placed in the detection cell to monitor the oxidation current of H2O2, and an ISE is placed in the sample cell to act as both the reference electrode and the potentiometric sensor for obtaining the ion activities. The oxidation of H2O2 is induced by a constant potential applied between the GC electrode and the ISE, and subsequently modulated by the potential change of the ISE in the presence of the primary ion. The proposed amperometric signal readout based on H2O2 shows the satisfied slope sensitivity and detection limit, which are better than or compared to those for the potentiometric responses for the ISEs. This work provides a general strategy for transforming the potential response of the ISEs into the amperometric readout, and is promising for detection of cations (eg., Ca2+) and anions (eg., NO3-) with high sensitivity and excellent selectivity.
WOS关键词SELECTIVE ELECTRODES ; ION ; MEMBRANE ; READOUT ; HEPARIN
资助项目National Natural Science Foundation of China[41706110] ; National Natural Science Foundation of China[U2006208] ; Key Project of the Natural Science Foundation of Shandong Province[ZR2020KF026] ; Key Deployment Project of Centre for Ocean Mega-Research of Science, Chinese Academy of Sciences[COMS2020J06] ; Taishan Scholar Program of Shandong Province[TSPD20181215] ; National Key Research and Development Program of China[2016YFC1400700]
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000658317000068
资助机构National Natural Science Foundation of China ; Key Project of the Natural Science Foundation of Shandong Province ; Key Deployment Project of Centre for Ocean Mega-Research of Science, Chinese Academy of Sciences ; Taishan Scholar Program of Shandong Province ; National Key Research and Development Program of China
源URL[http://ir.yic.ac.cn/handle/133337/29421]  
专题烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室
烟台海岸带研究所_近岸生态与环境实验室
通讯作者Yin, Tanji; Yuan, Baiqing
作者单位1.Chinese Acad Sci, Ctr Ocean Megasci, Qingdao 266071, Shandong, Peoples R China
2.Pilot Natl Lab Marine Sci & Technol, Lab Marine Biol & Biotechnol, Qingdao 26620, Peoples R China
3.Ludong Univ, Sch Chem & Mat Sci, Yantai 264025, Shandong, Peoples R China
4.YICCAS, Shandong Prov Key Lab Coastal Environm Proc, Yantai 264003, Shandong, Peoples R China
5.Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China
推荐引用方式
GB/T 7714		 Yin, Tanji,Wang, Hemin,Li, Jinghui,et al. Translating potentiometric detection into non-enzymatic amperometric measurement of H2O2[J]. TALANTA,2021,232:7.
APA Yin, Tanji,Wang, Hemin,Li, Jinghui,Yuan, Baiqing,&Qin, Wei.(2021).Translating potentiometric detection into non-enzymatic amperometric measurement of H2O2.TALANTA,232,7.
MLA Yin, Tanji,et al."Translating potentiometric detection into non-enzymatic amperometric measurement of H2O2".TALANTA 232(2021):7.

入库方式： OAI收割

来源：烟台海岸带研究所

浏览0
下载0
收藏0
其他版本

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。