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On-Off-On Fluorescent Chemosensors Based on N/P-Codoped Carbon Dots for Detection of Microcystin-LR

文献类型：期刊论文

作者Wang, Xiaoyan1; Yu, Jialuo2,3; Ji, Wan1; Arabi, Maryam2,3; Fu, Longwen2,3; Li, Bowei2,3; Chen, Lingxin1,2,3
刊名ACS APPLIED NANO MATERIALS
出版日期2021-07-23
卷号4期号:7页码:6852-6860
ISSN号2574-0970
关键词carbon dots microcystin-LR fluorescent chemosensors "on-off-on" mode indirect chemosensing
DOI10.1021/acsanm.1c00921
通讯作者Wang, Xiaoyan(wangxy@yic.ac.cn) ; Chen, Lingxin(lxchen@yic.ac.cn)
英文摘要The sensing of microcystin-LR (MC-LR) as a nonfluorescent species is still challenging since it has a negligible influence on the emission of fluorescent nanomaterials. Herein, a well-defined "on-off-on" indirect chemosensing strategy is developed by means of nitrogen/phosphorus-codoped carbon dots (N/P CDs) for highly sensitive and selective MC-LR determination. The nanoscale N/P CDs were conveniently synthesized by one-step hydrothermal carbonization of adenosine 5'-triphosphate (ATP) in aqueous media. The fluorescence intensity of the N/P CDs was quenched in the presence of Fe3+ due to the formation of Fe-O-P bonds between Fe3+ and the phosphate groups of the N/P CDs. The resulting N/P CD-Fe3+ system was sensitive to MC-LR, and its fluorescence intensity recovered dramatically and quickly since the MC-LR cavity competitively coordinated with Fe3+. Under optimized conditions, the proposed chemosensor exhibited a wide linear response for MC-LR in the range of 0.05-3 mu g/L, with a detection limit down to 17.1 ng/L. Moreover, the chemosensor was successfully applied to accurately detect MC-LR in real water samples and achieved high recoveries in the range of 95.0-109.3%, with relative standard deviations within 1.8-4.7%. By relying on the benefits of fluorescent chemosensors, such as simple operation, low production cost, fast response time, selectivity, and sensitivity, the proposed sensing platform possesses promising applicability for MC-LR determination in complex environmental water samples.
WOS关键词GRAPHENE QUANTUM DOTS ; SENSITIVE DETECTION ; ADENOSINE-TRIPHOSPHATE ; NITROGEN ; REMOVAL ; PROBE ; FE3+ ; NANOPARTICLES ; SENSORS ; ELISA
资助项目National Natural Science Foundation of China[21804010] ; National Natural Science Foundation of China[21575159] ; National Natural Science Foundation of China[41776110] ; National Natural Science Foundation of China[21976209] ; Science and Technology Innovation Development Plan of Yantai of China[2020YT06000898] ; Natural Science Foundation of Shandong Province[ZR2020QB105] ; Chinese Academy of Sciences President's International Fellowship Initiative[2019PC0050] ; Taishan Scholar Project Special Funding[ts20190962]
WOS研究方向Science & Technology - Other Topics ; Materials Science
语种英语
WOS记录号WOS:000677582900036
资助机构National Natural Science Foundation of China ; Science and Technology Innovation Development Plan of Yantai of China ; Natural Science Foundation of Shandong Province ; Chinese Academy of Sciences President's International Fellowship Initiative ; Taishan Scholar Project Special Funding
源URL[http://ir.yic.ac.cn/handle/133337/29539]  
专题烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室
烟台海岸带研究所_山东省海岸带环境工程技术研究中心
通讯作者Wang, Xiaoyan; Chen, Lingxin
作者单位1.Binzhou Med Univ, Sch Pharm, Yantai 264003, Peoples R China
2.Chinese Acad Sci, Ctr Ocean Megasci, Qingdao 266071, Peoples R China
3.Chinese Acad Sci, Yantai Inst Coastal Zone Res,Shandong Key Lab Coa, Res Ctr Coastal Environm Engn & Technol, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China
推荐引用方式
GB/T 7714		 Wang, Xiaoyan,Yu, Jialuo,Ji, Wan,et al. On-Off-On Fluorescent Chemosensors Based on N/P-Codoped Carbon Dots for Detection of Microcystin-LR[J]. ACS APPLIED NANO MATERIALS,2021,4(7):6852-6860.
APA Wang, Xiaoyan.,Yu, Jialuo.,Ji, Wan.,Arabi, Maryam.,Fu, Longwen.,...&Chen, Lingxin.(2021).On-Off-On Fluorescent Chemosensors Based on N/P-Codoped Carbon Dots for Detection of Microcystin-LR.ACS APPLIED NANO MATERIALS,4(7),6852-6860.
MLA Wang, Xiaoyan,et al."On-Off-On Fluorescent Chemosensors Based on N/P-Codoped Carbon Dots for Detection of Microcystin-LR".ACS APPLIED NANO MATERIALS 4.7(2021):6852-6860.

入库方式： OAI收割

来源：烟台海岸带研究所

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