中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Project Vienna: A Novel Precell Mass Filter for Collision/Reaction Cell MC-ICPMS/MS

文献类型:期刊论文

作者Craig, Grant2; Wehrs, Henning2; Bevan, Dan G.3; Pfeifer, Markus2; Lewis, Jamie3; Coath, Christopher D.3; Elliott, Tim3; Huang, Chao1,4; Lloyd, Nicholas S.2; Schwieters, Johannes B.2
刊名ANALYTICAL CHEMISTRY
出版日期2021-08-03
卷号93期号:30页码:10519-10527
ISSN号0003-2700
DOI10.1021/acs.analchem.1c01475
英文摘要The last decade has seen widespread adoption of triple quadrupole-based inductively coupled plasma-tandem mass spectrometry (ICPMS/MS) technique using a collision/reaction cell in combination with a precell bandpass mass analyzer to measure isotopes otherwise masked by spectral interferences. High-precision isotope ratio analysis containing such isotopes would benefit from a similar capability on a multicollector inductively coupled plasma mass spectrometry (MC-ICPMS) platform, but using a quadrupole-based precell mass analyzer for MC-ICPMS/MS has several limitations. To overcome these limitations, we developed a novel precell mass analyzer for MC-ICPMS/MS using sector field technology. The new precell mass analyzer, comprising two Wien filters and a selection aperture, and a hexapole collision/reaction cell were integrated together in a single module and added to the commercially available Thermo Scientific Neptune XT MC-ICPMS to create a prototype MC-ICPMS/MS we named Vienna. Vienna was proven to retain the same performance of the base MC-ICPMS in terms of sensitivity, accuracy, and precision. Using the Vienna mass filter to eliminate Ar-based species, the abundance sensitivity achievable was equivalent to TIMS at mass 237.05, which was used to accurately determine the low U-236/U-238 isotope ratio of the uranium reference material IRMM184 (certified value, 1.2446 x 10(-7)). The performance of Vienna was then tested for a variety of geoscience applications that were expected to benefit from MC-ICPMS/MS technique, including Ca, K, Si, and in situ Rb/Sr dating by laser ablation.
WOS关键词INDUCTIVELY-COUPLED PLASMA ; ISOTOPE FRACTIONATION ; SR ; SPECTROMETRY ; LITHIUM ; SAMPLES ; RATIOS
资助项目NERC[NE/P010342]
WOS研究方向Chemistry
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000683353300018
资助机构NERC ; NERC ; NERC ; NERC ; NERC ; NERC ; NERC ; NERC
源URL[http://ir.iggcas.ac.cn/handle/132A11/101893]  
专题地质与地球物理研究所_岩石圈演化国家重点实验室
通讯作者Craig, Grant
作者单位1.Chinese Acad Sci, Inst Geol & Geophys, State Key Lab Lithospher Evolut, Beijing 100029, Peoples R China
2.Thermo Fisher Sci Bremen GmbH, D-28199 Bremen, Germany
3.Univ Bristol, Sch Earth Sci, Bristol BS8 1RJ, Avon, England
4.Chinese Acad Sci, Innovat Acad Earth Sci, Beijing 100029, Peoples R China
推荐引用方式
GB/T 7714
Craig, Grant,Wehrs, Henning,Bevan, Dan G.,et al. Project Vienna: A Novel Precell Mass Filter for Collision/Reaction Cell MC-ICPMS/MS[J]. ANALYTICAL CHEMISTRY,2021,93(30):10519-10527.
APA Craig, Grant.,Wehrs, Henning.,Bevan, Dan G..,Pfeifer, Markus.,Lewis, Jamie.,...&Schwieters, Johannes B..(2021).Project Vienna: A Novel Precell Mass Filter for Collision/Reaction Cell MC-ICPMS/MS.ANALYTICAL CHEMISTRY,93(30),10519-10527.
MLA Craig, Grant,et al."Project Vienna: A Novel Precell Mass Filter for Collision/Reaction Cell MC-ICPMS/MS".ANALYTICAL CHEMISTRY 93.30(2021):10519-10527.

入库方式: OAI收割

来源:地质与地球物理研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。