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Geochemistry of vapor-dominated hydrothermal vent deposits in Yellowstone Lake, Wyoming

文献类型:期刊论文

作者Tudor, Amanda2; Fowler, Andrew2; Foustoukos, Dionysis I.3; Moskowitz, Bruce2; Wang, Liheng1; Tan, Chunyang2; Seyfried Jr, William E.2
刊名JOURNAL OF VOLCANOLOGY AND GEOTHERMAL RESEARCH
出版日期2021-06-01
卷号414页码:15
关键词Yellowstone Lake Hydrothermal deposits Vent fluid chemistry Mineral alteration Reaction rates
ISSN号0377-0273
DOI10.1016/j.jvolgeores.2021.107231
英文摘要Yellowstone Lake hydrothermal vent systems have been studied using ROV assets to better understand the chemical and mineralogical evolution of the sublacustrine sediments through which the hot spring fluids discharge to the lake floor. Here we focus on the deposits/alteration and coexisting vent fluid chemistry associated with the Deep Hole on the lake floor, east of Stevenson Island. Remote in its location, at 120 m below the lake surface, this region in the northeast portion of Yellowstone Lake is associated with numerous hydrothermal vents and hot springs, providing evidence of high-temperature fluid-mineral interaction and phase separation phenomena. Vapor-dominated hydrothermal fluids issuing from Deep Hole vents attain temperatures in excess of 150 degrees C and are enriched in magmatically derived H2S and CO2. Upon mixing with lake water in the root zone of the hydrothermally active vents, the dissolved gases render the mixed fluid, both acidic and reducing, effectively transforming diatomaceous sediment, with detritally sourced Al and Fe components, to an alteration assemblage dominated by kaolinite, pyrite, and lesser boehmite. These alteration processes have been modeled by computer based simulations, coupling fluid flow and mineral dissolution kinetics, to provide insight on the temporal evolution of the vent system. Results predict rapid dissolution of amorphous silica. The magnitude and rate of silica loss, facilitated by the continuous influx of acidic source fluids, yields an increasingly silica poor alteration mineral sequence with time, characterized by quartz, followed by kaolinite and ultimately boehmite. These data are consistent with the observed decrease in SiO2/Al2O3 ratio of the vent deposits with increasing abundance of trace immobile elements, suggesting significant mass loss with reaction progress. Pyrite is predicted to form from sulfidation of magnetite, with noteworthy decrease in magnetic intensity, as measured for hydrothermally altered sediment in the near-field vent environment. Moreover, hydrogen isotope compositional data for kaolinite, together with delta D vent fluid data, suggest temperatures in keeping with the high temperatures measured for the vent deposits and discharging fluid, while supporting the potential use of kaolinite as a geothermometer. The predicted and observed transformation of silica-rich protolith to kaolinite, boehmite, and pyrite underscores the large scale dissolution and removal of silica, with possible implications for the temporal evolution of vent deposits on the lake floor in the Stevenson Island Deep-Hole region. Published by Elsevier B.V.
WOS关键词HYDROGEN ISOTOPE FRACTIONATION ; THERMODYNAMIC PROPERTIES ; PRECIPITATION KINETICS ; DISSOLUTION KINETICS ; REDOX REACTIONS ; CLAY-MINERALS ; WATER ; SYSTEMS ; KAOLINITE ; CONSTRAINTS
资助项目NSF[EAR 1515377] ; NSF[OCE 1434798] ; NSF[EAR 1761388] ; NSF Division of Earth Sciences, Instruments and Facilities program ; University of Minnesota
WOS研究方向Geology
语种英语
WOS记录号WOS:000646275100007
出版者ELSEVIER
资助机构NSF ; NSF ; NSF Division of Earth Sciences, Instruments and Facilities program ; NSF Division of Earth Sciences, Instruments and Facilities program ; University of Minnesota ; University of Minnesota ; NSF ; NSF ; NSF Division of Earth Sciences, Instruments and Facilities program ; NSF Division of Earth Sciences, Instruments and Facilities program ; University of Minnesota ; University of Minnesota ; NSF ; NSF ; NSF Division of Earth Sciences, Instruments and Facilities program ; NSF Division of Earth Sciences, Instruments and Facilities program ; University of Minnesota ; University of Minnesota ; NSF ; NSF ; NSF Division of Earth Sciences, Instruments and Facilities program ; NSF Division of Earth Sciences, Instruments and Facilities program ; University of Minnesota ; University of Minnesota
源URL[http://ir.iggcas.ac.cn/handle/132A11/101197]  
专题地质与地球物理研究所_中国科学院页岩气与地质工程重点实验室
通讯作者Tan, Chunyang
作者单位1.Chinese Acad Sci, Inst Geol & Geophys, Key Lab Shale Gas & Geoengn, Beijing 100029, Peoples R China
2.Univ Minnesota, Dept Earth & Environm Sci, Minneapolis, MN 55455 USA
3.Carnegie Inst Sci, Earth & Planets Lab, 5241 Broad Branch Rd NW, Washington, DC 20015 USA
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Tudor, Amanda,Fowler, Andrew,Foustoukos, Dionysis I.,et al. Geochemistry of vapor-dominated hydrothermal vent deposits in Yellowstone Lake, Wyoming[J]. JOURNAL OF VOLCANOLOGY AND GEOTHERMAL RESEARCH,2021,414:15.
APA Tudor, Amanda.,Fowler, Andrew.,Foustoukos, Dionysis I..,Moskowitz, Bruce.,Wang, Liheng.,...&Seyfried Jr, William E..(2021).Geochemistry of vapor-dominated hydrothermal vent deposits in Yellowstone Lake, Wyoming.JOURNAL OF VOLCANOLOGY AND GEOTHERMAL RESEARCH,414,15.
MLA Tudor, Amanda,et al."Geochemistry of vapor-dominated hydrothermal vent deposits in Yellowstone Lake, Wyoming".JOURNAL OF VOLCANOLOGY AND GEOTHERMAL RESEARCH 414(2021):15.

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来源:地质与地球物理研究所

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