A facile solution-phase synthetic approach for constructing phenol-based porous organic cages and covalent organic frameworks
文献类型：期刊论文
| 作者 | Zhang, L; Liang, RR; Hang, C; Wang, HY; Sun, L; Xu, L; Liu, DR; Zhang, ZY; Zhang, XM; Chang, FF |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2020 |
| 卷号 | 22期号:8页码:2498-2504 |
| 关键词 | MOLECULAR CAGE CRYSTALLINE WATER ADSORPTION NETWORKS CARBONS CO2 |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/c9gc04033a |
| 文献子类 | 期刊论文 |
| 英文摘要 | Porous crystalline materials, such as porous organic cages (POCs) and covalent organic frameworks (COFs), are important for a wide range of applications such as gas storage/separation, sensing and catalysis. A conventional synthetic approach for imine-based POCs and COFs usually involves the use of organic solvents/acid catalysts (such as AcOH or TFA). However, synthesizing and growing POC crystals and COF crystallites with enhanced crystallinity is not an easy-to-perform process, in which many reaction parameters need to be screened. To overcome these problems, we have proposed herein a facile and green synthetic strategy by adopting H2O/organic solvents/MOH (M = Na, K, and Cs) as reaction media to produce a series of phenol-based POCs and COFs. X-ray crystallography and molecular simulations have been used to confirm their structures in addition to NMR, mass and FT-IR spectra, and gas sorption experiments reveal their porosity and sorption properties. This new approach provides not only an efficient and alternative route to synthesize highly crystalline POCs and even COFs, but also insight into the crystallization process of these two kinds of porous materials, especially in the hydrous media. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/32676]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Bruker Sci Technol Co Ltd, 66 Xixiaokou Rd, Beijing 100081, Peoples R China 2.Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing Natl Lab Microstruct, Nanjing 210093, Jiangsu, Peoples R China 3.Yancheng Inst Technol, Key Lab Adv Technol Environm Protect Jiangsu Pro, Yancheng 224051, Peoples R China 4.Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Synthet & Self Assembly Chem Organ Funct, 345 Lingling Rd, Shanghai 200032, Peoples R China 5.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, 239 Zhangheng Rd, Pudong New Area 201204, Peoples R China 6.Nanjing Univ, Shenzhen Res Inst, Shenzhen 518057, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, L,Liang, RR,Hang, C,et al. A facile solution-phase synthetic approach for constructing phenol-based porous organic cages and covalent organic frameworks[J]. GREEN CHEMISTRY,2020,22(8):2498-2504. |
| APA | Zhang, L.,Liang, RR.,Hang, C.,Wang, HY.,Sun, L.,...&Huang, W.(2020).A facile solution-phase synthetic approach for constructing phenol-based porous organic cages and covalent organic frameworks.GREEN CHEMISTRY,22(8),2498-2504. |
| MLA | Zhang, L,et al."A facile solution-phase synthetic approach for constructing phenol-based porous organic cages and covalent organic frameworks".GREEN CHEMISTRY 22.8(2020):2498-2504. |
入库方式： OAI收割
来源：上海应用物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。