Design of a Single-Atom Indium(delta+)-N(4)Interface for Efficient Electroreduction of CO(2)to Formate
文献类型：期刊论文
| 作者 | Shang, HS; Wang, T; Pei, JJ; Jiang, ZL; Zhou, DN; Wang, Y; Li, HJ; Dong, JC; Zhuang, ZB; Chen, WX |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2020 |
| 卷号 | 59期号:50页码:22465-22469 |
| 关键词 | SELECTIVE ELECTROCHEMICAL REDUCTION ELECTROCATALYTIC CO2 REDUCTION METAL-ORGANIC FRAMEWORK CARBON-DIOXIDE FORMIC-ACID CATALYSTS |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.202010903 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Main-group element indium (In) is a promising electrocatalyst which triggers CO(2)reduction to formate, while the high overpotential and low Faradaic efficiency (FE) hinder its practical application. Herein, we rationally design a new In single-atom catalyst containing exclusive isolated In delta+-N(4)atomic interface sites for CO(2)electroreduction to formate with high efficiency. This catalyst exhibits an extremely large turnover frequency (TOF) up to 12500 h(-1)at -0.95 V versus the reversible hydrogen electrode (RHE), with a FE for formate of 96 % and current density of 8.87 mA cm(-2)at low potential of -0.65 V versus RHE. Our findings present a feasible strategy for the accurate regulation of main-group indium catalysts for CO(2)reduction at atomic scale. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/32783]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Beijing Univ Chem Technol, Beijing Adv Innovat Ctr Soft Matter Sci & Engn, Beijing 100029, Peoples R China 2.Chinese Acad Sci, Beijing Synchrotron Radiat Facil, Inst High Energy Phys, Beijing 100029, Peoples R China 3.Chinese Acad Sci, Shanghai Synchrotron Radiat Facil, Shanghai Inst Appl Phys, Shanghai 201204, Peoples R China 4.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China 5.Beijing Inst Technol, Beijing Key Lab Construct Tailorable Adv Funct Ma, Sch Mat Sci & Engn, Beijing 100081, Peoples R China 6.Stanford Univ, Dept Chem Engn, SUNCAT Ctr Interface Sci & Catalysis, Stanford, CA 94305 USA 7.Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shang, HS,Wang, T,Pei, JJ,et al. Design of a Single-Atom Indium(delta+)-N(4)Interface for Efficient Electroreduction of CO(2)to Formate[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2020,59(50):22465-22469. |
| APA | Shang, HS.,Wang, T.,Pei, JJ.,Jiang, ZL.,Zhou, DN.,...&Li, YD.(2020).Design of a Single-Atom Indium(delta+)-N(4)Interface for Efficient Electroreduction of CO(2)to Formate.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,59(50),22465-22469. |
| MLA | Shang, HS,et al."Design of a Single-Atom Indium(delta+)-N(4)Interface for Efficient Electroreduction of CO(2)to Formate".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 59.50(2020):22465-22469. |
入库方式： OAI收割
来源：上海应用物理研究所
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