Electron Beam Irradiation as a General Approach for the Rapid Synthesis of Covalent Organic Frameworks under Ambient Conditions
文献类型：期刊论文
| 作者 | Zhang, MX; Chen, JC; Zhang, ST; Zhou, XQ; He, LW; Sheridan, MV; Yuan, MJ; Zhang, MJ; Chen, L; Dai, X |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2020 |
| 卷号 | 142期号:20页码:9169-9174 |
| ISSN号 | 0002-7863 |
| 关键词 | CRYSTALLINE |
| DOI | 10.1021/jacs.0c03941 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Crystalline porous materials such as covalent organic frameworks (COFs) are advanced materials to tackle challenges of catalysis and separation in industrial processes. Their synthetic routes often require elevated temperatures, closed systems with high pressure, and long reaction times, hampering their industrial applications. Here we use a traditionally unperceived strategy to assemble highly crystalline COFs by electron beam irradiation with controlled received dosage, contrasting sharply with the previous observation that radiation damages the crystallinity of solids. Such synthesis by electron beam irradiation can be achieved under ambient conditions within minutes, and the process is amendable for large-scale production. The intense and targeted energy input to the reactants leads to new reaction pathways that favor COF formation in nearly quantitative yield. This strategy is applicable not only to known COFs but also to new series of flexible COFs that are difficult to obtain using traditional methods. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/32841]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA 2.Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China 3.Soochow Univ, State Key Lab Radiat Med & Protect, Sch Radiol & Interdisciplinary Sci RAD X, Suzhou 215123, Peoples R China 4.Soochow Univ, Collaborat Innovat Ctr Med Jiangsu Higher Educ In, Suzhou 215123, Peoples R China 5.Shanghai Inst Appl Phys, CAS Ctr Excellence TMSR Energy Syst, Shanghai 201800, Peoples R China 6.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, MX,Chen, JC,Zhang, ST,et al. Electron Beam Irradiation as a General Approach for the Rapid Synthesis of Covalent Organic Frameworks under Ambient Conditions[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2020,142(20):9169-9174. |
| APA | Zhang, MX.,Chen, JC.,Zhang, ST.,Zhou, XQ.,He, LW.,...&Wang, S.(2020).Electron Beam Irradiation as a General Approach for the Rapid Synthesis of Covalent Organic Frameworks under Ambient Conditions.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,142(20),9169-9174. |
| MLA | Zhang, MX,et al."Electron Beam Irradiation as a General Approach for the Rapid Synthesis of Covalent Organic Frameworks under Ambient Conditions".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 142.20(2020):9169-9174. |
入库方式： OAI收割
来源：上海应用物理研究所
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