Enhancing CO(2)Electroreduction to Methane with a Cobalt Phthalocyanine and Zinc-Nitrogen-Carbon Tandem Catalyst
文献类型：期刊论文
| 作者 | Lin, L; Liu, TF; Xiao, JP; Li, HF; Wei, PF; Gao, DF; Nan, B; Si, R; Wang, GX; Bao, XH |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2020 |
| 卷号 | 59期号:50页码:22408-22413 |
| 关键词 | SINGLE-ATOM CATALYSTS CO2 REDUCTION ELECTROCHEMICAL REDUCTION DIOXIDE REDUCTION ELECTROREDUCTION SITES ELECTROCATALYSTS OXYGEN |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.202009191 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Developing copper-free catalysts for CO(2)conversion into hydrocarbons and oxygenates is highly desirable for electrochemical CO(2)reduction reaction (CO2RR). Herein, we report a cobalt phthalocyanine (CoPc) and zinc-nitrogen-carbon (Zn-N-C) tandem catalyst for CO2RR to CH4. This tandem catalyst shows a more than 100 times enhancement of the CH4/CO production rate ratio compared with CoPc or Zn-N-C alone. Density functional theory (DFT) calculations and electrochemical CO reduction reaction results suggest that CO(2)is first reduced into CO over CoPc and then CO diffuses onto Zn-N-C for further conversion into CH(4)over Zn-N(4)site, decoupling complicated CO2RR pathway on single active site into a two-step tandem reaction. Moreover, mechanistic analysis indicates that CoPc not only generates CO but also enhances the availability of *H over adjacent N sites in Zn-N-4, which is the key to achieve the high CH(4)production rate and understand the intriguing electrocatalytic behavior which is distinctive to copper-based tandem catalysts. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/32859]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lin, L,Liu, TF,Xiao, JP,et al. Enhancing CO(2)Electroreduction to Methane with a Cobalt Phthalocyanine and Zinc-Nitrogen-Carbon Tandem Catalyst[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2020,59(50):22408-22413. |
| APA | Lin, L.,Liu, TF.,Xiao, JP.,Li, HF.,Wei, PF.,...&Bao, XH.(2020).Enhancing CO(2)Electroreduction to Methane with a Cobalt Phthalocyanine and Zinc-Nitrogen-Carbon Tandem Catalyst.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,59(50),22408-22413. |
| MLA | Lin, L,et al."Enhancing CO(2)Electroreduction to Methane with a Cobalt Phthalocyanine and Zinc-Nitrogen-Carbon Tandem Catalyst".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 59.50(2020):22408-22413. |
入库方式： OAI收割
来源：上海应用物理研究所
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