In situ synthesis and characterization of a series of new pyridyl containing complexes based on 3d metals: from oligomer to 3D framework
文献类型：期刊论文
| 作者 | Weng, ZH; Xiang, PZ; Ling, J; Huang, MX; Yang, WF; Zheng, ZF; Deng, XJ; Ju, HD; Huang, Y |
| 刊名 | JOURNAL OF SOLID STATE CHEMISTRY
 |
| 出版日期 | 2020 |
| 卷号 | 287页码:- |
| ISSN号 | 0022-4596 |
| 关键词 | COORDINATION POLYMERS ORGANIC FRAMEWORKS CRYSTAL-STRUCTURES HYDROTHERMAL SYNTHESIS 5-SUBSTITUTED 1H-TETRAZOLES FLUORESCENCE PROPERTIES LUMINESCENT PROPERTIES TETRAZOLE LIGAND FAMILY |
| DOI | 10.1016/j.jssc.2020.121326 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Five coordination compounds assembled from the pyridyl based ligand, Ni(PBN)(4)(N-3)(2), 1; {[Co(PPT)(2)center dot(H2O)(2)]center dot 2H(2)O](n), 2; [Cu(PPT)](n) 3; {[Zn-2(PPT)(3)(OH)]center dot 2H(2)O}n, 4, and [Cd(PPT)(2)](n) 5 (PPT = 5-(3-pyridylphenyl)tetrazole and PBN = 4-(3-pyridyl)benzonitrile) have been solvothermally synthesized and characterized by single-crystal X-ray diffraction, powder XRD, elemental analysis, IR spectroscopy, solid state fluorescence and TG analysis. The PPT ligand in the complexes is generated via the in situ [2 + 3] cycloaddition in the reaction of the cyano groups of the organonitrile and sodium azide. Single-crystal X-ray diffraction analyses reveal compound 1 is an oligomer of 6-coordinated Ni(II) compound where the 6 coordination sites are occupied by six nitrogen atoms from four distinct PBN ligands and two azide ions, respectively. Compound 2 exhibits a 1D chain structure where the 6-coordinated cobalt centers are double connected by two upside down mu(2)-PPT ligands. Both compound 3 and compound 4 present the 2D sheet structures constructed by mu(2)-tetrazole-linked copper(I) dimmer and mu 2-hydroxyconnected zinc(II) dimmer, respectively, with both centers of 4-coordinated fashions. Compound 5 is a dense 3D framework with the PPT ligand of a mu(3)-bridging mode. Structural analyses indicate the structural varieties of the dimensionalities in these compounds result from the coordination diversity of the PPT ligands. In addition, compound 3 represents a rare example of copper(II) that is experienced the self-reduction process during the in situ [2 + 3] cycloaddition and exhibits a blue emission at room temperature. Thermal stability analyses indicate the compounds 4 and 5 are stable up to 300 degrees C and the temperature dependent PXRD reveal the residues of compounds 4 and 5 are ZnO and CdCO3, respectively. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/32930]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Claflin Univ, Dept Chem & Biochem, Orangeburg, SC 29115 USA 2.Kunming Univ, Sch Chem & Chem Engn, Kunming 650214, Yunnan, Peoples R China 3.Yunnan Open Univ, Sch Chem Engn, Kunming 650223, Yunnan, Peoples R China 4.Chinese Acad Sci, Shanghai Inst Appl Phys, 2019 Jia Luo Rd, Shanghai 201800, Peoples R China |
| 推荐引用方式 GB/T 7714 | Weng, ZH,Xiang, PZ,Ling, J,et al. In situ synthesis and characterization of a series of new pyridyl containing complexes based on 3d metals: from oligomer to 3D framework[J]. JOURNAL OF SOLID STATE CHEMISTRY,2020,287:-. |
| APA | Weng, ZH.,Xiang, PZ.,Ling, J.,Huang, MX.,Yang, WF.,...&Huang, Y.(2020).In situ synthesis and characterization of a series of new pyridyl containing complexes based on 3d metals: from oligomer to 3D framework.JOURNAL OF SOLID STATE CHEMISTRY,287,-. |
| MLA | Weng, ZH,et al."In situ synthesis and characterization of a series of new pyridyl containing complexes based on 3d metals: from oligomer to 3D framework".JOURNAL OF SOLID STATE CHEMISTRY 287(2020):-. |
入库方式： OAI收割
来源：上海应用物理研究所
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