Local nearly non-strained perovskite lattice approaching a broad environmental stability window of efficient solar cells
文献类型：期刊论文
| 作者 | Xu, J; Dong, H; Xi, J; Yang, YG; Yu, Y; Ma, L; Chen, JB; Jiao, B; Hou, X; Li, JR |
| 刊名 | NANO ENERGY
 |
| 出版日期 | 2020 |
| 卷号 | 75页码:- |
| ISSN号 | 2211-2855 |
| 关键词 | HALIDE PEROVSKITES PASSIVATION PERFORMANCE |
| DOI | 10.1016/j.nanoen.2020.104940 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Twist and fracture of surface lattice tend to occur under harsh condition due to the soft lattice natures of hybrid perovskite materials. Accordingly, surface defects and lattice distortion are produced, which allow the performance loss and notorious degradation in perovskite solar cells (PSCs). In our work, judiciously selected conjugated ligand was employed as the film intermediary, from which rigid and delocalization 4-phenylpyridine (4-pPy) exhibited the most significant improvement on both optoelectrical performance and stability of PSCs. By regulating the film crystallization kinetics, high-quality perovskite films can be obtained with preferable crystal orientation. Moreover, benefiting from the defects passivation and unidirectional bonding effect, coordinated 4pPy "scaffold" on the lattice surface could mitigate vacancy formation and lattice twist/fracture under severe conditions. The resulted p-i-n planar device shows a considerable PCE of 21.12% (certified 20.2%) with negligible hysteresis, as well as an excellent storage (90% of original PCE after 1000 h at 60% RH), operating (90% of original PCE after 600 h at maximum power point) and thermal stress (89% of original PCE after 500 h at 85 degrees C) stability. It is hoped that our findings could open a new way to accelerate continued progress on PSCs regimes for efficieny maximization and stability prolongation. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/32980]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Xi An Jiao Tong Univ, Sch Elect Sci & Engn, Minist Educ, Elect Mat Res Lab,Key Lab, Xian 710049, Peoples R China 2.ShanxiUniv, Collaborat Innovat Ctr Extreme Opt, Taiyuan 030006, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China 4.Univ Groningen, Zernike Inst Adv Mat, Nijenborgh 4, NL-9747 AG Groningen, Netherlands 5.Xidian Univ, Sch Phys & Optoelect Engn, Xian 710071, Peoples R China 6.Xi An Jiao Tong Univ, Sch Elect & Informat Engn, Minist Educ, Key Lab Phys Elect & Devices, 28 Xianning West Rd, Xian 710049, Peoples R China 7.Xi An Jiao Tong Univ, Sch Elect & Informat Engn, Shaanxi Key Lab Informat Photon Tech, 28 Xianning West Rd, Xian 710049, Peoples R China 8.Xi An Jiao Tong Univ, Sch Elect Sci & Engn, Int Ctr Dielect Res, Xian 710049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, J,Dong, H,Xi, J,et al. Local nearly non-strained perovskite lattice approaching a broad environmental stability window of efficient solar cells[J]. NANO ENERGY,2020,75:-. |
| APA | Xu, J.,Dong, H.,Xi, J.,Yang, YG.,Yu, Y.,...&Wu, ZX.(2020).Local nearly non-strained perovskite lattice approaching a broad environmental stability window of efficient solar cells.NANO ENERGY,75,-. |
| MLA | Xu, J,et al."Local nearly non-strained perovskite lattice approaching a broad environmental stability window of efficient solar cells".NANO ENERGY 75(2020):-. |
入库方式： OAI收割
来源：上海应用物理研究所
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