Stable Interface between a NaCl-AlCl3 Melt and a Liquid Ga Negative Electrode for a Long-Life Stationary Al-Ion Energy Storage Battery
文献类型：期刊论文
| 作者 | Wang, JX; Jiao, HD; Song, WL; Wang, MY; Tu, JG; Tang, ZF; Zhu, HM |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2020 |
| 卷号 | 12期号:13页码:15063-15070 |
| 关键词 | ALUMINUM UNDERPOTENTIAL DEPOSITION CATHODE MATERIAL ALLOY FORMATION |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/acsami.9b21809 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Intermediate temperature NaCl-AlCl3-based Al-ion batteries are considered as a promising stationary energy storage system due to their low cost, high safety, etc. However, such a cheap electrolyte has a critical feature, i.e., strong corrosion, which results in the short cycle life of the conventional Al-metal anode and also limits the development of the NaCl-AlCl3-based Al-ion batteries. A noncorrosive electrolyte may be a good choice for addressing the above challenge, while it is difficult to obtain the electrolyte that has advantages of both noncorrosion and low cost. Therefore, here, we report a Ga-metal anode in the affordable NaCl-AlCl3 electrolyte for constructing a long-life stationary Al-ion energy storage system. This featured liquid metal anode shows good alloying and dealloying processes between metallic Ga and Al, as well as renders superior stability of the interface between the electrolyte and the anode (e.g., smoothly running for over 580 h at 2 mA cm(-2)). No-corrosion and no-pulverization problems appear in this novel liquid/liquid interface. Those advantages demonstrate that the liquid Ga-metal anode has a great promise for the improvement of the NaCl-AlCl3-based AIl-ion batteries for large-scale stationary energy storage applications. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/33149]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Univ Sci & Technol Beijing, State Key Lab Adv Met, Beijing 100083, Peoples R China 2.Beijing Inst Technol, Inst Adv Struct Technol, Beijing 100081, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, JX,Jiao, HD,Song, WL,et al. Stable Interface between a NaCl-AlCl3 Melt and a Liquid Ga Negative Electrode for a Long-Life Stationary Al-Ion Energy Storage Battery[J]. ACS APPLIED MATERIALS & INTERFACES,2020,12(13):15063-15070. |
| APA | Wang, JX.,Jiao, HD.,Song, WL.,Wang, MY.,Tu, JG.,...&Zhu, HM.(2020).Stable Interface between a NaCl-AlCl3 Melt and a Liquid Ga Negative Electrode for a Long-Life Stationary Al-Ion Energy Storage Battery.ACS APPLIED MATERIALS & INTERFACES,12(13),15063-15070. |
| MLA | Wang, JX,et al."Stable Interface between a NaCl-AlCl3 Melt and a Liquid Ga Negative Electrode for a Long-Life Stationary Al-Ion Energy Storage Battery".ACS APPLIED MATERIALS & INTERFACES 12.13(2020):15063-15070. |
入库方式： OAI收割
来源：上海应用物理研究所
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