Structural Complexity and Magnetic Orderings in a Large Family of 3d-4f Heterobimetallic Sulfates
文献类型：期刊论文
| 作者 | Lu, HJ; Diefenbach, K; Li, ZJ; Bao, HL; Guo, XF; Wang, JQ; Albrecht-Schmitt, TE; Lin, J |
| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2020 |
| 卷号 | 59期号:18页码:13398-13406 |
| 关键词 | LANTHANIDE NI CO FRAMEWORKS TB MN LN |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/acs.inorgchem.0c01765 |
| 文献子类 | 期刊论文 |
| 英文摘要 | The synthesis of a large family of heterobimetallic lanthanide copper sulfates was realized via stoichiometric hydrothermal reactions among Ln(2)O(3), CuO, and H2SO4, giving rise to four distinct phases, namely Ln(2)Cu(SO4)(2)(OH)(4) (Ln = Sm-Ho) (LnCuSO(4)-1), Ln(4)Cu(SO4)(2)(OH)(10) (Ln = Tm-Lu) (LnCuSO(4)-2), LnCu(SO4)(OH)(3) (Ln = Nd-Gd, except Pm) (LnCuSO(4)-3), and LnCu(SO4)(OH)(3) (Ln = Dy-Lu) (LnCuSO(4)-4), with completely different topologies. The passage from LnCuSO(4)-1 and LnCuSO(4)-3 to LnCuSO(4)-2 and LnCuSO(4)-4 across the 4f series, respectively, can be ascribed to the effect of lanthanide contraction, which progressively induces shrinking of the Ln-O distance, reduction in the Ln coordination number, and eventually structural transitions. The incorporation of identical 3d-4f metal ions into different spin-lattices, in conjunction with substitution of diverse Ln(3+) cations within the same spin-lattice, gives rise to tunable magnetic properties varying from ferromagnetic ordering in GdCuSO4-3 and HoCuSO4-4 to antiferromagnetic ordering in YbCuSO4-4, and to paramagnetic correlations found in GdCuSO4-1 and YbCuSO4-2. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/33155]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA 2.Univ Chinese Acad Sci, Shijingshan Dist, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Shanghai 201800, Peoples R China 4.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 5.Washington State Univ, Alexandra Navrotsky Inst Expt Thermodynam, Washington, WA 99164 USA 6.Washington State Univ, Dept Chem, Washington, WA 99164 USA |
| 推荐引用方式 GB/T 7714 | Lu, HJ,Diefenbach, K,Li, ZJ,et al. Structural Complexity and Magnetic Orderings in a Large Family of 3d-4f Heterobimetallic Sulfates[J]. INORGANIC CHEMISTRY,2020,59(18):13398-13406. |
| APA | Lu, HJ.,Diefenbach, K.,Li, ZJ.,Bao, HL.,Guo, XF.,...&Lin, J.(2020).Structural Complexity and Magnetic Orderings in a Large Family of 3d-4f Heterobimetallic Sulfates.INORGANIC CHEMISTRY,59(18),13398-13406. |
| MLA | Lu, HJ,et al."Structural Complexity and Magnetic Orderings in a Large Family of 3d-4f Heterobimetallic Sulfates".INORGANIC CHEMISTRY 59.18(2020):13398-13406. |
入库方式： OAI收割
来源：上海应用物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。