Sulfur-substituted uranyl stabilized by fluoride ligands: matrix preparation of U(O)(S)F(2)viaoxidation of U(0) by SOF2
文献类型：期刊论文
| 作者 | Wei, R; Chen, XT; Gong, Y |
| 刊名 | CHEMICAL COMMUNICATIONS
 |
| 出版日期 | 2020 |
| 卷号 | 56期号:50页码:6782-6785 |
| 关键词 | INFRARED-SPECTRA ELECTRONIC-STRUCTURE IMIDO ANALOGS COMPLEXES MOLECULES SINGLE ATOMS ION OXO NH2 |
| ISSN号 | 1359-7345 |
| DOI | 10.1039/d0cc03139a |
| 文献子类 | 期刊论文 |
| 英文摘要 | A fluoride stabilized sulfur-substituted uranyl complex [U(O)(S)F-2] was prepared for the first timeviaoxidation of U(0) by SOF(2)in cryogenic matrixes. The electron withdrawing character of F in this neutral complex does not cause the oxidation of the sulfido ligand by U(vi), but increases the strength and covalency of the U-O and U-S bonds. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/33173]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Appl Phys, Dept Radiochem, Shanghai 201800, Peoples R China 2.Univ Chinese Acad Sci, Sch Nucl Sci & Technol, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wei, R,Chen, XT,Gong, Y. Sulfur-substituted uranyl stabilized by fluoride ligands: matrix preparation of U(O)(S)F(2)viaoxidation of U(0) by SOF2[J]. CHEMICAL COMMUNICATIONS,2020,56(50):6782-6785. |
| APA | Wei, R,Chen, XT,&Gong, Y.(2020).Sulfur-substituted uranyl stabilized by fluoride ligands: matrix preparation of U(O)(S)F(2)viaoxidation of U(0) by SOF2.CHEMICAL COMMUNICATIONS,56(50),6782-6785. |
| MLA | Wei, R,et al."Sulfur-substituted uranyl stabilized by fluoride ligands: matrix preparation of U(O)(S)F(2)viaoxidation of U(0) by SOF2".CHEMICAL COMMUNICATIONS 56.50(2020):6782-6785. |
入库方式： OAI收割
来源：上海应用物理研究所
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