The investigation of molten ZnCl2 natural particle suspensions
文献类型:期刊论文
作者 | Wang, XL; Liu, YY; Shen, M; Fu, XB; Han, L; Ma, GH; Liu, HT; Yan, L |
刊名 | ANALYTICAL METHODS |
出版日期 | 2020 |
卷号 | 12期号:9页码:1229-1236 |
ISSN号 | 1759-9660 |
关键词 | CORROSION BEHAVIOR CHLORIDE LIGHT ATTENUATION SCATTERING SOLVENTS RHEOLOGY STORAGE DEPOSIT ALLOYS |
DOI | 10.1039/c9ay02680k |
文献子类 | 期刊论文 |
英文摘要 | The common but unexpectedly neglected natural particle suspensions (NPSs) have significant effects on the characteristics of molten salts. In the present work, NPSs were generated via the corrosion of Cr or Fe cubes in molten ZnCl2 at 370, 420 or 470 degrees C in air and then investigated using in situ ultraviolet-visible spectroscopy, infrared spectroscopy and inductively coupled plasma optical emission spectrometry. The behaviors of Cr and Fe in these systems were quite different. In the case of Cr, particle (mainly contained Cr2O3) sizes grew over time and temperature. The elemental concentrations of Cr also increased over time; in addition, its values at 420 degrees C were slightly larger than that at 370 degrees C but much lower than that at 470 degrees C. For Fe, particle (mainly contained Fe2O3) sizes and elemental concentrations of Fe decreased with temperature, whereas they first increased (the time required for the increase reduced with temperature) and then decreased slowly over time. These results can be ascribed to the chemical reactions of these metals with the molten salts and/or various impurities. |
语种 | 英语 |
源URL | [http://ir.sinap.ac.cn/handle/331007/33194] |
专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
作者单位 | 1.Shanghai Univ, Dept Phys, Shanghai 200444, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Shanghai 201800, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, XL,Liu, YY,Shen, M,et al. The investigation of molten ZnCl2 natural particle suspensions[J]. ANALYTICAL METHODS,2020,12(9):1229-1236. |
APA | Wang, XL.,Liu, YY.,Shen, M.,Fu, XB.,Han, L.,...&Yan, L.(2020).The investigation of molten ZnCl2 natural particle suspensions.ANALYTICAL METHODS,12(9),1229-1236. |
MLA | Wang, XL,et al."The investigation of molten ZnCl2 natural particle suspensions".ANALYTICAL METHODS 12.9(2020):1229-1236. |
入库方式: OAI收割
来源:上海应用物理研究所
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