Understanding the origin of high oxygen evolution reaction activity in the high Sr-doped perovskite
文献类型：期刊论文
| 作者 | Song, SZ; Zhou, J; Sun, J; Zhang, SY; Lin, X; Hu, ZW; Hu, J; Zhang, LJ; Wang, JQ |
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2020 |
| 卷号 | 41期号:4页码:592-597 |
| 关键词 | WATER OXIDATION SELF-RECONSTRUCTION CATALYSTS ELECTROCATALYSTS ABSORPTION TRACKING SURFACE |
| ISSN号 | 0253-9837 |
| DOI | 10.1016/S1872-2067(19)63441-8 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Effective electrocatalysis is crucial for enhancing the efficiency of water splitting to obtain clean fuels. Herein, we report a system of interesting and high-performance Sr-doped perovskite electrocatalysts with porous structures, obtained via a facile molten salt method and applied in the oxygen evolution reaction (OER). With increasing the Sr content, the valence states of Co and Fe ions do not clearly increase, according to the Co-L-2,L-3 and Fe-L-2,L-3 as well as the Co-K and the Fe-K X-ray absorption spectroscopy, whereas doped holes are clearly observed in the O-K edge. High-resolution transmission electron microscopy indicates the appearance of an amorphous layer after the electrochemical reaction. We conclude that the formation of the amorphous layer at the surface, induced by Sr doping, is crucial for achieving high OER activity, and we offer insights into the self-reconstruction of the OER catalyst. (C) 2020, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/33249]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Shanghai 201800, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China 4.Max Planck Inst Chem Phys Solids, Nothnitzer Str 40, D-01187 Dresden, Germany |
| 推荐引用方式 GB/T 7714 | Song, SZ,Zhou, J,Sun, J,et al. Understanding the origin of high oxygen evolution reaction activity in the high Sr-doped perovskite[J]. CHINESE JOURNAL OF CATALYSIS,2020,41(4):592-597. |
| APA | Song, SZ.,Zhou, J.,Sun, J.,Zhang, SY.,Lin, X.,...&Wang, JQ.(2020).Understanding the origin of high oxygen evolution reaction activity in the high Sr-doped perovskite.CHINESE JOURNAL OF CATALYSIS,41(4),592-597. |
| MLA | Song, SZ,et al."Understanding the origin of high oxygen evolution reaction activity in the high Sr-doped perovskite".CHINESE JOURNAL OF CATALYSIS 41.4(2020):592-597. |
入库方式： OAI收割
来源：上海应用物理研究所
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