Metal-free visible-light-induced aerobic oxidation of alpha-diazoesters leading to alpha-ketoesters in air
文献类型：期刊论文
| 作者 | Liu, Ruisheng; Liu, Qishun; Meng, Haoran; Ding, Hongyu; Hao, Jindong; Ji, Zhongyin; Yue, Huilan; Wei, Wei |
| 刊名 | ORGANIC CHEMISTRY FRONTIERS
 |
| 出版日期 | 2021 |
| 卷号 | 8期号:9 |
| 英文摘要 | A metal-free and visible-light-promoted strategy has been achieved for the construction of alpha-ketoesters via aerobic oxidation of alpha-diazoesters with dioxygen in air at room temperature. Using cheap, readily available Eosin Y as the photocatalyst and O-2(air) as the green oxidant, the present protocol offers a mild and efficient approach to a wide range of alpha-ketoesters in moderate to good yields. Preliminary mechanistic studies suggested that photo-excited singlet oxygen was involved in the present reaction system. |
| 源URL | [http://210.75.249.4/handle/363003/60807]  |
| 专题 | 西北高原生物研究所_中国科学院西北高原生物研究所 |
| 推荐引用方式 GB/T 7714 | Liu, Ruisheng,Liu, Qishun,Meng, Haoran,et al. Metal-free visible-light-induced aerobic oxidation of alpha-diazoesters leading to alpha-ketoesters in air[J]. ORGANIC CHEMISTRY FRONTIERS,2021,8(9). |
| APA | Liu, Ruisheng.,Liu, Qishun.,Meng, Haoran.,Ding, Hongyu.,Hao, Jindong.,...&Wei, Wei.(2021).Metal-free visible-light-induced aerobic oxidation of alpha-diazoesters leading to alpha-ketoesters in air.ORGANIC CHEMISTRY FRONTIERS,8(9). |
| MLA | Liu, Ruisheng,et al."Metal-free visible-light-induced aerobic oxidation of alpha-diazoesters leading to alpha-ketoesters in air".ORGANIC CHEMISTRY FRONTIERS 8.9(2021). |
入库方式： OAI收割
来源：西北高原生物研究所
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