Catalyst-Free and Transition-Metal-Free Approach to 1,2-Diketones via Aerobic Alkyne Oxidation
文献类型：期刊论文
| 作者 | Shen, Duyi; Wang, Hongyan; Zheng, Yanan; Zhu, Xinjing; Gong, Peiwei; Wang, Bin; You, Jinmao ; Zhao, Yulei; Chao, Mianran
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| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
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| 出版日期 | 2021 |
| 卷号 | 86期号:7 |
| 英文摘要 | A catalyst-free and transition-metal-free method for the synthesis of 1,2-diketones from aerobic alkyne oxidation was reported. The oxidation of various internal alkynes, especially more challenging aryl-alkyl acetylenes, proceeded smoothly with inexpensive, easily handled, and commercially available potassium persulfate and an ambient air balloon, achieving the corresponding 1,2-diketones with up to 85% yields. Meanwhile, mechanistic studies indicated a radical process, and the two oxygen atoms in the 1,2-diketons were most likely from persulfate salts and molecular oxygen, respectively, rather than water. |
| 源URL | [http://210.75.249.4/handle/363003/60821]  |
| 专题 | 西北高原生物研究所_中国科学院西北高原生物研究所 |
| 推荐引用方式 GB/T 7714 | Shen, Duyi,Wang, Hongyan,Zheng, Yanan,et al. Catalyst-Free and Transition-Metal-Free Approach to 1,2-Diketones via Aerobic Alkyne Oxidation[J]. JOURNAL OF ORGANIC CHEMISTRY,2021,86(7). |
| APA | Shen, Duyi.,Wang, Hongyan.,Zheng, Yanan.,Zhu, Xinjing.,Gong, Peiwei.,...&Chao, Mianran.(2021).Catalyst-Free and Transition-Metal-Free Approach to 1,2-Diketones via Aerobic Alkyne Oxidation.JOURNAL OF ORGANIC CHEMISTRY,86(7). |
| MLA | Shen, Duyi,et al."Catalyst-Free and Transition-Metal-Free Approach to 1,2-Diketones via Aerobic Alkyne Oxidation".JOURNAL OF ORGANIC CHEMISTRY 86.7(2021). |
入库方式： OAI收割
来源：西北高原生物研究所
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