Visible-light-promoted sulfonylation of thiols with aryldiazonium and sodium metabisulphite leading to unsymmetrical thiosulfonates dagger
文献类型：期刊论文
| 作者 | Lv, Yufen; Luo, Jinyun; Ma, Yuchuan; Dong, Qi; He, Lin |
| 刊名 | ORGANIC CHEMISTRY FRONTIERS
 |
| 出版日期 | 2021 |
| 卷号 | 8期号:11 |
| 英文摘要 | A new visible-light-mediated protocol has been proposed for the synthesis of thiosulfonates via metal-free sulfonylation of thiols with aryldiazonium and sodium metabisulphite at room temperature. This mild three-component reaction simply utilizes readily available rhodamine 6G as the photocatalyst and cheap inorganic sulfite of sodium metabisulfite as a SO2 surrogate and provides an attractive strategy to access various unsymmetrical thiosulfonates in moderate to good yields under oxidant- or strong acid-free conditions. Preliminary mechanistic studies indicated that a radical pathway was involved in the present transformation. |
| 源URL | [http://210.75.249.4/handle/363003/60833]  |
| 专题 | 西北高原生物研究所_中国科学院西北高原生物研究所 |
| 推荐引用方式 GB/T 7714 | Lv, Yufen,Luo, Jinyun,Ma, Yuchuan,et al. Visible-light-promoted sulfonylation of thiols with aryldiazonium and sodium metabisulphite leading to unsymmetrical thiosulfonates dagger[J]. ORGANIC CHEMISTRY FRONTIERS,2021,8(11). |
| APA | Lv, Yufen,Luo, Jinyun,Ma, Yuchuan,Dong, Qi,&He, Lin.(2021).Visible-light-promoted sulfonylation of thiols with aryldiazonium and sodium metabisulphite leading to unsymmetrical thiosulfonates dagger.ORGANIC CHEMISTRY FRONTIERS,8(11). |
| MLA | Lv, Yufen,et al."Visible-light-promoted sulfonylation of thiols with aryldiazonium and sodium metabisulphite leading to unsymmetrical thiosulfonates dagger".ORGANIC CHEMISTRY FRONTIERS 8.11(2021). |
入库方式： OAI收割
来源：西北高原生物研究所
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