Superconductivity in efficient thermoelectric material Cu3Sb0.98Al0.02Se4
文献类型:期刊论文
作者 | Zhao, Xiaomiao1,2; Zhou, Yonghui3![]() ![]() |
刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
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出版日期 | 2021-01-15 |
卷号 | 890 |
关键词 | High-pressure Superconductivity Structural transition Hall coefficient |
ISSN号 | 0925-8388 |
DOI | 10.1016/j.jallcom.2021.161828 |
通讯作者 | Chen, Xiaojia(xjchen@hpstar.ac.cn) |
英文摘要 | Inspired by the rich physical properties of thermoelectric materials, we have investigated the electrical transport, vibrational, and structural properties of efficient thermoelectric material Cu3Sb0.98Al0.02Se4 under pressure up to 40.1 GPa. At a critical pressure of 8.5 GPa, a superconducting phase sets in and persists in the pressure range studied. A superconducting dome in the temperature-pressure phase diagram of Cu3Sb0.98Al0.02Se4 was observed. Meanwhile, pressure-induced structural transition from its initial phase to disorder body-centered cubic structure in Cu3Sb0.98Al0.02Se4 has been verified by the X-ray diffraction and Raman scattering measurements. Interestingly, the onset of superconductivity coincides with the structural transition, accompanied with the reduction of volume. The superconducting phase was observed in the ultimate formation of the Cu-Sb-Al-Se alloy and was determined to be Im-3m. Based on Hall coefficient measurements, we evaluated the carrier concentration of Cu3Sb0.98Al0.02Se4, which shows a dramatic increase in the superconducting state. These results suggest that the novel superconductor is realized through the charge transfers and the first-order structural transformation. (C) 2021 Elsevier B.V. All rights reserved. |
WOS关键词 | TEMPERATURE ; CU3SBSE4 ; TRANSITION ; HYDRIDE ; KELVIN ; SN ; CU |
资助项目 | Key Scientific and Technological Research Projects in Henan Province[212102210114] |
WOS研究方向 | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
语种 | 英语 |
WOS记录号 | WOS:000706379700001 |
出版者 | ELSEVIER SCIENCE SA |
资助机构 | Key Scientific and Technological Research Projects in Henan Province |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/125513] ![]() |
专题 | 中国科学院合肥物质科学研究院 |
通讯作者 | Chen, Xiaojia |
作者单位 | 1.Henan Univ Technol, Coll Mat Sci & Engn, Zhengzhou 450001, Peoples R China 2.Ctr High Pressure Sci & Technol Adv Res, Shanghai 201203, Peoples R China 3.Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Peoples R China 4.Carnegie Inst Sci, Geophys Lab, Washington, DC 20015 USA 5.Russian Acad Sci, Inst Nucl Res, Troitsk 108840, Russia 6.Russian Acad Sci, FSRC Crystallog & Photon, Moscow 119333, Russia 7.Immanuel Kant Baltic Fed Univ, REC Funct Nanomat, Kaliningrad 236041, Russia |
推荐引用方式 GB/T 7714 | Zhao, Xiaomiao,Zhou, Yonghui,Struzhkin, Viktor V.,et al. Superconductivity in efficient thermoelectric material Cu3Sb0.98Al0.02Se4[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2021,890. |
APA | Zhao, Xiaomiao.,Zhou, Yonghui.,Struzhkin, Viktor V..,Mao, Ho-Kwang.,Gavriliuk, Alexander G..,...&Chen, Xiaojia.(2021).Superconductivity in efficient thermoelectric material Cu3Sb0.98Al0.02Se4.JOURNAL OF ALLOYS AND COMPOUNDS,890. |
MLA | Zhao, Xiaomiao,et al."Superconductivity in efficient thermoelectric material Cu3Sb0.98Al0.02Se4".JOURNAL OF ALLOYS AND COMPOUNDS 890(2021). |
入库方式: OAI收割
来源:合肥物质科学研究院
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