In Situ Synthesis of Cu Nanoparticles on Carbon for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol by Using Pomelo Peel as the Carbon Source
文献类型：期刊论文
| 作者 | Wang, Chenguang1,2; Liu, Yong3; Cui, Zhibing4; Yu, Xiaohu5; Zhang, Xinghua1,2 ; Li, Yuping1,2; Zhang, Qi1,2; Chen, Lungang1,2; Ma, Longlong1,2
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| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
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| 出版日期 | 2020-08-31 |
| 卷号 | 8期号:34页码:12944-12955 |
| 关键词 | furfural hydrogenation Cu nanoparticles furfuryl alcohol pomelo peel DFT |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.0c03505 |
| 通讯作者 | Chen, Lungang(chenlg1981@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn) |
| 英文摘要 | A facile approach was developed to directly synthesize carbon-supported metal nanoparticles with pomelo peel as the carbon source and metal nitrate solution as the metal source. Fe/C, Co/C, Ni/C, and Cu/C catalysts were prepared after calcination in N-2 without further reduction. The metal nanoparticles and formation mechanism were investigated by multiple techniques such as XRD, HRTEM, XPS, FTIR spectra, SEM, and TG-MS thermal analysis. In the case of furfural hydrogenation, Cu/C catalyst exhibited the best activity and exclusive selectivity to produce furfuryl alcohol with complete conversion, and excellent selectivity can be maintained at a higher temperature of 240 degrees C. The particle size of Cu nanoparticles can be tuned by the calcination temperature and metal loading for improving catalytic activity. The excellent performance of Cu nanoparticles was also studied by density functional theory calculation, agreeing well with the experiments. |
| WOS关键词 | LIQUID-PHASE HYDROGENATION ; CATALYTIC TRANSFER HYDROGENATION ; BIOMASS ; NI ; CONVERSION ; TRANSFORMATION ; 2-METHYLFURAN ; ACTIVATION ; ROUTES ; METAL |
| 资助项目 | National Key R&D Program of China[2019YFD1100601] ; National Natural Science Foundation of China[21878290] ; Natural Science Foundation of Guangdong Province[2017A030313073] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000567778600023 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China ; Natural Science Foundation of Guangdong Province |
| 源URL | [http://ir.giec.ac.cn/handle/344007/32014]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Chen, Lungang; Ma, Longlong |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 2.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 3.Univ New Hampshire, Dept Chem Engn, Durham, NH 03824 USA 4.Zhengzhou Univ, Sch Chem Engn & Energy, Zhengzhou 450001, Peoples R China 5.Shaanxi Univ Technol, Sch Chem & Environm Sci, Inst Theoret & Computat Chem, Shaanxi Key Lab Catalysis, Hanzhong 723000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Chenguang,Liu, Yong,Cui, Zhibing,et al. In Situ Synthesis of Cu Nanoparticles on Carbon for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol by Using Pomelo Peel as the Carbon Source[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2020,8(34):12944-12955. |
| APA | Wang, Chenguang.,Liu, Yong.,Cui, Zhibing.,Yu, Xiaohu.,Zhang, Xinghua.,...&Ma, Longlong.(2020).In Situ Synthesis of Cu Nanoparticles on Carbon for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol by Using Pomelo Peel as the Carbon Source.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,8(34),12944-12955. |
| MLA | Wang, Chenguang,et al."In Situ Synthesis of Cu Nanoparticles on Carbon for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol by Using Pomelo Peel as the Carbon Source".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 8.34(2020):12944-12955. |
入库方式： OAI收割
来源：广州能源研究所
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