Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC-MS/MS
文献类型：期刊论文
| 作者 | Shi, Ning1,2,3; Liu, Qiying1,2 ; Liu, Ying3; Chen, Lijun3; Zhang, Hongyan3; Huang, Hongsheng3; Ma, Longlong1,2
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| 刊名 | ACS OMEGA
 |
| 出版日期 | 2020-09-15 |
| 卷号 | 5期号:36页码:23322-23333 |
| ISSN号 | 2470-1343 |
| DOI | 10.1021/acsomega.0c03169 |
| 通讯作者 | Shi, Ning(shining@git.edu.cn) |
| 英文摘要 | To reveal the hydrothermal conversion routes of the biomass-derived furanic compounds, the soluble products formed during the hydrothermal conversion of 5-hydroxymethylfurfural (HMF), furfural, and furfuryl alcohol were analyzed by liquid chromatography-mass spectrometry (LC-MS) and LC-MS/MS. Multiple carbocyclic compounds containing hydroxy group and carbonyl group were detected, with a molecular mass in the range of 154-272 Da and carbon chain of the length 8-15. The formation of these soluble carbocyclic compounds was proposed to involve hydrolytic ring-opening of the furanic ring, intermolecular aldol condensation, intramolecular aldol condensation, and C-C cleavage reaction. The C-C cleavage reaction was proposed to occur on the dicarbonyl structure of the formed primary polymers. |
| WOS关键词 | MAILLARD REACTION CASCADE ; CARBOXYLIC-ACIDS ; SUGAR FRAGMENTATION ; LEVULINIC ACID ; LACTIC-ACID ; HUMINS ; DEGRADATION ; CELLULOSE ; CATALYST ; MECHANISM |
| 资助项目 | Natural Science Foundation of Guizhou Province[QiankeheJichu [2020] 1Y239] ; High Level Scientific Research Funding Project of Guizhou Institute of Technology[XJGC20190636] ; Academic New Seedling Plan Project of Guizhou Institute of Technology[QianKeHe [2017]5789-08] ; Natural Science Foundation of Guizhou Provincial Department of Education[Qianjiaohe KY Zi [2016]014] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000572832600069 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | Natural Science Foundation of Guizhou Province ; High Level Scientific Research Funding Project of Guizhou Institute of Technology ; Academic New Seedling Plan Project of Guizhou Institute of Technology ; Natural Science Foundation of Guizhou Provincial Department of Education |
| 源URL | [http://ir.giec.ac.cn/handle/344007/32065]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Shi, Ning |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 3.Guizhou Inst Technol, Sch Chem Engn, Guiyang 550003, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, Ning,Liu, Qiying,Liu, Ying,et al. Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC-MS/MS[J]. ACS OMEGA,2020,5(36):23322-23333. |
| APA | Shi, Ning.,Liu, Qiying.,Liu, Ying.,Chen, Lijun.,Zhang, Hongyan.,...&Ma, Longlong.(2020).Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC-MS/MS.ACS OMEGA,5(36),23322-23333. |
| MLA | Shi, Ning,et al."Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC-MS/MS".ACS OMEGA 5.36(2020):23322-23333. |
入库方式： OAI收割
来源：广州能源研究所
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