Conversion of Glucose into 5-Hydroxymethylfurfural and Levulinic Acid Catalyzed by SO42-/ZrO2 in a Biphasic Solvent System
文献类型：期刊论文
| 作者 | Qu, Yang2; Zhao, Yuan1; Xiong, Shanshan2; Wang, Chenguang3; Wang, Shurong2; Zhu, Lingjun2; Ma, Longlong3
|
| 刊名 | ENERGY & FUELS
 |
| 出版日期 | 2020-09-17 |
| 卷号 | 34期号:9页码:11041-11049 |
| ISSN号 | 0887-0624 |
| DOI | 10.1021/acs.energyfuels.0c01823 |
| 通讯作者 | Wang, Chenguang(wangcg@ms.giec.ac.cn) ; Wang, Shurong(srwang@zju.edu.cn) ; Ma, Longlong(mall@ms.giec.ac.cn) |
| 英文摘要 | 5-Hydroxymethylfurfural (HMF) and levulinic acid (LA) are two important platform compounds that can be produced by the dehydration of hexoses from hydrolysis of cellulose. In this study, glucose dehydration was catalyzed by the SO42-/ZrO2 catalyst in the NaCl-THF/H2O biphasic solvent system. Complete conversion of glucose was achieved at 160 degrees C. The highest HMF yield and LA yield were 61.84% and 29.68%, respectively. The results showed that the conversion and product distribution were influenced by catalyst acidity, solvent composition, temperature, and time. The SO42- load greatly changed the acidity of the catalyst, thus affecting the product distribution. By changing the composition of the catalyst and the biphasic solvent system, different yields of HMF and LA could be obtained, so as to realize directional synthesis of the target products. |
| WOS关键词 | HOT COMPRESSED WATER ; FURAN-DERIVATIVES ; BIOMASS ; FRUCTOSE ; LEWIS ; DEHYDRATION ; CELLULOSE ; ROUTES ; SUGARS ; OXIDE |
| 资助项目 | National Key R&D Program of China[2018YFB1501500] |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000574904900052 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Key R&D Program of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/32128]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Wang, Chenguang; Wang, Shurong; Ma, Longlong |
| 作者单位 | 1.Powerchina HuaDong Engn Corp Ltd, Hangzhou 311122, Peoples R China 2.Zhejiang Univ, State Key Lab Clean Energy Utilizat, Hangzhou 310027, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qu, Yang,Zhao, Yuan,Xiong, Shanshan,et al. Conversion of Glucose into 5-Hydroxymethylfurfural and Levulinic Acid Catalyzed by SO42-/ZrO2 in a Biphasic Solvent System[J]. ENERGY & FUELS,2020,34(9):11041-11049. |
| APA | Qu, Yang.,Zhao, Yuan.,Xiong, Shanshan.,Wang, Chenguang.,Wang, Shurong.,...&Ma, Longlong.(2020).Conversion of Glucose into 5-Hydroxymethylfurfural and Levulinic Acid Catalyzed by SO42-/ZrO2 in a Biphasic Solvent System.ENERGY & FUELS,34(9),11041-11049. |
| MLA | Qu, Yang,et al."Conversion of Glucose into 5-Hydroxymethylfurfural and Levulinic Acid Catalyzed by SO42-/ZrO2 in a Biphasic Solvent System".ENERGY & FUELS 34.9(2020):11041-11049. |
入库方式： OAI收割
来源：广州能源研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。