Selective C-3-C-4 Keto-Alcohol Production from Cellulose Hydrogenolysis over Ni-WOx/C Catalysts
文献类型：期刊论文
| 作者 | Wang, Haiyong2,3,4; Xin, Haosheng2,3,4,5; Cai, Chiliu2,3,4 ; Zhu, Changhui2,3,4,5; Xiu, Zhongxun2,3,4,5; Liu, Qiying2,3,4,6; Weng, Yujing1,2,3,4; Wang, Chenguang2,3,4; Zhang, Xinghua2,3,4; Liu, Shijun2,3,4
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| 刊名 | ACS CATALYSIS
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| 出版日期 | 2020-09-18 |
| 卷号 | 10期号:18页码:10646-10660 |
| ISSN号 | 2155-5435 |
| 关键词 | biomass cellulose keto-alcohols Ni-WOx/C catalyst hydrogenolysis |
| DOI | 10.1021/acscatal.0c02375 |
| 通讯作者 | Liu, Qiying(liuqy@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.gies.ac.cn) |
| 英文摘要 | Keto-alcohols, which are traditionally produced from fossil resources with multisteps, are considered as important intermediates for diversified high-value-added fine chemical synthesis due to their involved carbonyl and hydroxyl groups. Herein, direct cellulose hydrogenolysis to C-3-C-4 keto-alcohol products (hydroxyacetone and 1(3)hydroxy-2-butanone) was achieved over Ni-WOx/C catalysts with an W/Ni atom ratio of 1.0-5.0. The keto-alcohol yield was proposed to strongly depend on the W/Ni ratio and the catalyst annealing temperature. The highest keto-alcohol yield of 63% was obtained at the optimal balance of basic/acidic WOx species and metallic Ni. The introduction of Ni facilitated the formation of the basic W5+ sites, which enhanced the formation of basic sites at the Ni-WOx interface. The synergistic effect between the basic W5+ and acidic oxygen vacancy (Vo) could activate the target C-O/C=O bonds, promoting the isomerization of glucose and C-3-C-4 aldehyde intermediates with the assistance of the interfacial Ni. The cooperative adsorption of the -OH and -C=O groups at the Ni-O-W-Vo interface stabilized the adjacent ketone and hydroxyl groups and kept the other hydroxyl groups for hydrogenolysis, obtaining the final C-3-C-4 keto-alcohols. This work expanded the application of cellulosic biomass, enabling the green and sustainable synthesis of the high-value C-3-C-4 keto-alcohol products using lignocellulosic biomass as a raw material. |
| WOS关键词 | INITIO MOLECULAR-DYNAMICS ; TOTAL-ENERGY CALCULATIONS ; ETHYLENE-GLYCOL ; MICROCRYSTALLINE CELLULOSE ; PHOTOCATALYTIC OXIDATION ; DIRECT CONVERSION ; TUNGSTEN CARBIDE ; BIOMASS ; RUTHENIUM ; GLUCOSE |
| 资助项目 | National Key Research and Development Program of China[2018YFB1501402] ; National Natural Science Foundation of China[51536009] ; National Natural Science Foundation of China[51976220] ; Natural Science Foundation of Guangdong Province[2017A030308010] ; DNL Cooperation Fund, CAS[DNL180302] ; Strategic Priority Research Program of the Chinese Academy of Science[XDA21060102] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092] ; Guangdong Key Laboratory of New and Renewable Energy Research and Development[Y807s51001] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000574920200036 |
| 资助机构 | National Key Research and Development Program of China ; National Natural Science Foundation of China ; Natural Science Foundation of Guangdong Province ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Science ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program ; Guangdong Key Laboratory of New and Renewable Energy Research and Development |
| 源URL | [http://ir.giec.ac.cn/handle/344007/32168]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Liu, Qiying; Ma, Longlong |
| 作者单位 | 1.Henan Polytech Univ, Coll Chem & Chem Engn, Jiaozuo 454000, Henan, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 3.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 4.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Peoples R China 5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 6.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Haiyong,Xin, Haosheng,Cai, Chiliu,et al. Selective C-3-C-4 Keto-Alcohol Production from Cellulose Hydrogenolysis over Ni-WOx/C Catalysts[J]. ACS CATALYSIS,2020,10(18):10646-10660. |
| APA | Wang, Haiyong.,Xin, Haosheng.,Cai, Chiliu.,Zhu, Changhui.,Xiu, Zhongxun.,...&Ma, Longlong.(2020).Selective C-3-C-4 Keto-Alcohol Production from Cellulose Hydrogenolysis over Ni-WOx/C Catalysts.ACS CATALYSIS,10(18),10646-10660. |
| MLA | Wang, Haiyong,et al."Selective C-3-C-4 Keto-Alcohol Production from Cellulose Hydrogenolysis over Ni-WOx/C Catalysts".ACS CATALYSIS 10.18(2020):10646-10660. |
入库方式： OAI收割
来源：广州能源研究所
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