Upcycling biomass tar into highly porous, defective and pyridinic-n-enriched graphene nanohybrid as efficient bifunctional catalyst for Zn-air battery
文献类型：期刊论文
| 作者 | Li, Denian1,3,4; Chen, Huibing1,3,5; Zhang, Yuyuan2; Yang, Jizhang1,3; Yuan, Haoran1,2,3,4,5 ; Chen, Yong1,3,4,5
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| 刊名 | ELECTROCHIMICA ACTA
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| 出版日期 | 2020-12-20 |
| 卷号 | 364页码:10 |
| 关键词 | Biomass tar Graphene nanohybrids Bifunctional oxygen-electrocatalyst Zn-air battery |
| ISSN号 | 0013-4686 |
| DOI | 10.1016/j.electacta.2020.137319 |
| 通讯作者 | Yuan, Haoran(yuanhr@ms.giec.ac.cn) |
| 英文摘要 | With quite limited use, biomass tar has been a long-standing issue that strongly impaired the cost-efficiency of biomass gasification. Here, a facile activation-annealing route for upcycling biomass tar into graphene nanohybrids with developed porosity and enriched pyridinic nitrogen was reported, whilst the metal-free product revealed with superior catalytic activities to the benchmark Pt/C and RuO2 catalysts toward oxygen reduction reaction (ORR) and evolution reaction (OER). By associating the dual functionalities with products' physiochemical properties, it was unveiled that those pyridinic-N and defects were accounted for the promoted oxygen reduction and evolution, respectively. Together with reinforced electric conductivity and hierarchical porosity and enlarged interface via ammonia annealing, the heterogeneously structured carbon catalyst finally endowed an assembled primary Zn-air battery with maximum energy density of 121 mW/cm(-2), in addition to robust stability against long-term running. This work highlights the great potential of biomass tar for advanced carbon materials, and therefore a novel strategy to address the tar-related challenges faced by gasification technologies. (C) 2020 Elsevier Ltd. All rights reserved. |
| WOS关键词 | OXYGEN REDUCTION REACTION ; DOPED MESOPOROUS CARBON ; METAL-FREE CATALYSTS ; FREE ELECTRODE ; ACTIVE-SITES ; NITROGEN ; EVOLUTION ; ELECTROCATALYSTS ; NANOSHEETS ; RICH |
| 资助项目 | National Key R&D Program of China[2018YFC1901200] ; National Natural Science Foundation of China[5180622G] ; Provincial Natural Science of Guangdong[2019A1515] ; Provincial Natural Science of Guangdong[J11570] ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou)[GAIL2019Z00101] |
| WOS研究方向 | Electrochemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000591745300002 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China ; Provincial Natural Science of Guangdong ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) |
| 源URL | [http://ir.giec.ac.cn/handle/344007/32358]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Yuan, Haoran |
| 作者单位 | 1.Chinese Acad Sci, Guangdong Prov Key Lab New & Renewable Energy Res, Key Lab Renewable Energy, Guangzhou, Peoples R China 2.Foshan Univ, Sch Mat & Energy, Foshan 528225, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Lab Integrated Technol Urban & Rural Mines Exploi, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China 4.Southern Marine Sci & Engn Guangdong Lab Guangzho, Guangzhou 511458, Peoples R China 5.Changzhou Univ, Inst Urban & Rural Min, Sch Petrochem Engn, Changzhou 213164, Jiangsu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Denian,Chen, Huibing,Zhang, Yuyuan,et al. Upcycling biomass tar into highly porous, defective and pyridinic-n-enriched graphene nanohybrid as efficient bifunctional catalyst for Zn-air battery[J]. ELECTROCHIMICA ACTA,2020,364:10. |
| APA | Li, Denian,Chen, Huibing,Zhang, Yuyuan,Yang, Jizhang,Yuan, Haoran,&Chen, Yong.(2020).Upcycling biomass tar into highly porous, defective and pyridinic-n-enriched graphene nanohybrid as efficient bifunctional catalyst for Zn-air battery.ELECTROCHIMICA ACTA,364,10. |
| MLA | Li, Denian,et al."Upcycling biomass tar into highly porous, defective and pyridinic-n-enriched graphene nanohybrid as efficient bifunctional catalyst for Zn-air battery".ELECTROCHIMICA ACTA 364(2020):10. |
入库方式： OAI收割
来源：广州能源研究所
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