Crosslinkable aqueous binders containing Arabic gum-grafted-poly (acrylic acid) and branched polyols for Si anode of lithium-ion batteries
文献类型：期刊论文
| 作者 | Zhong, Haoxiang2; He, Jiarong1,2; Zhang, Lingzhi2
|
| 刊名 | POLYMER
 |
| 出版日期 | 2021-02-12 |
| 卷号 | 215页码:7 |
| 关键词 | Aqueous binder Crosslinking network Silicon anode |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/j.polymer.2020.123377 |
| 通讯作者 | Zhang, Lingzhi(lzzhang@ms.giec.ac.cn) |
| 英文摘要 | Arabic gum grafted poly (acrylic acid) (GA-g-PAA) is prepared through a free radical graft polymerization of acrylic acid onto Arabic gum. Crosslinkable aqueous binder is developed by combining GA-g-PAA and branched polyols (pentaerythrotol, PER; triethanolamine, TEOA) as crosslinking agent for Si anodes of lithium-ion batteries. The aqueous composite binder undergoes crosslinking at about 110 degrees C to form robust crosslinked networks, matching well with the processing temperature of the electrode sheet in industry. GA-g-PAA/PER binder displays higher adhesion strength than GA-g-PAA and GA-g-PAA/TEOA. The Si electrode with GA-g-PAA/PER exhibits a slightly better cycling stability at 0.2C for 100 cycles, better rate capability than GA-g-PAA and GA-g-PAA/TEOA. At a high rate of 1C, Si electrode with GA-g-PAA/P delivers a higher specific capacity of 1968.1 mAhg(-1) with a better capacity retention of 57.5% when compared with those with GA-g-PAA and GA-g-PAA/T binder. |
| 资助项目 | K.C.Wong Education Foundation ; National Natural Science Foundation of China[22075288] ; National Natural Science Foundation of China[21573239] ; Science & Technology Project of Guangdong Province[2015B010135008] ; Natural Science Foundation of Guangdong Province[2015A030313721] |
| WOS研究方向 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000618218300005 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | K.C.Wong Education Foundation ; National Natural Science Foundation of China ; Science & Technology Project of Guangdong Province ; Natural Science Foundation of Guangdong Province |
| 源URL | [http://ir.giec.ac.cn/handle/344007/32668]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Zhang, Lingzhi |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou Inst Energy Convers, 2 Nengyuan Rd, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhong, Haoxiang,He, Jiarong,Zhang, Lingzhi. Crosslinkable aqueous binders containing Arabic gum-grafted-poly (acrylic acid) and branched polyols for Si anode of lithium-ion batteries[J]. POLYMER,2021,215:7. |
| APA | Zhong, Haoxiang,He, Jiarong,&Zhang, Lingzhi.(2021).Crosslinkable aqueous binders containing Arabic gum-grafted-poly (acrylic acid) and branched polyols for Si anode of lithium-ion batteries.POLYMER,215,7. |
| MLA | Zhong, Haoxiang,et al."Crosslinkable aqueous binders containing Arabic gum-grafted-poly (acrylic acid) and branched polyols for Si anode of lithium-ion batteries".POLYMER 215(2021):7. |
入库方式： OAI收割
来源：广州能源研究所
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