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Synthesis of High-Density Components of Jet Fuel from Lignin-Derived Aromatics via Alkylation and Subsequent Hydrodeoxygenation

文献类型：期刊论文

作者Bai, Jing1,4; Zhang, Yang1,2; Zhang, Xinghua2,3; Wang, Chenguang2; Ma, Longlong2
刊名ACS SUSTAINABLE CHEMISTRY & ENGINEERING
出版日期2021-05-24
卷号9期号:20页码:7112-7119
关键词biomass alkylation hydrodeoxygenation dicyclohexylmethane perhydrofluorene high-density jet fuel
ISSN号2168-0485
DOI10.1021/acssuschemeng.1c01339
通讯作者Zhang, Xinghua(zhangxh@ms.giec.ac.cn) ; Wang, Chenguang(wangcg@ms.giec.ac.cn)
英文摘要High-density polycyclic alkanes prepared from lignocellulose biomass are an important substitute for fossil fuels. Here, we reported a synthesis strategy in that lignin-derived phenol and benzyl acetate were used to synthesize jet fuel-range high-density alkanes. Benzylphenols (C13-oxygenated compounds) were synthesized through the alkylation reaction of phenol and benzyl acetate over a montmorillonite (MMT) catalyst. The lewis acid site of MMT is favorable for the formation of the benzyl cation, promoting the alkylation reaction. Under the conditions of 140 degrees C and 2 h, the yield of alkylation products reaches 70%. Subsequently, the hydrodeoxygenation (HDO) of alkylation products was conducted over a 5 wt % Pd/C catalyst, and the yield of 85% hydrocarbons was obtained. Perhydrofluorene and dicyclohexylmethane were the dominant components in the HDO products. The density and heating values of HDO products were 0.956 g/cm(3) and 38.9 MJ/L, respectively.
WOS关键词RANGE ALKANES ; ACID SITES ; BENZYLATION ; AVIATION ; PYROLYSIS ; CATALYST ; BENZENE ; BIOFUEL ; BIOMASS ; PHENOL
资助项目National Natural Science Foundation of China[51876210] ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences[XDA21060102] ; local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092] ; Special Support Program of Guangdong Province for Top Young Talents[2019TQ05L238]
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Engineering
语种英语
WOS记录号WOS:000656120600019
出版者AMER CHEMICAL SOC
资助机构National Natural Science Foundation of China ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences ; local Innovative and Research Teams Project of Guangdong Pearl River Talents Program ; Special Support Program of Guangdong Province for Top Young Talents
源URL[http://ir.giec.ac.cn/handle/344007/33307]  
专题中国科学院广州能源研究所
通讯作者Zhang, Xinghua; Wang, Chenguang
作者单位1.Zhengzhou Univ, Sch Chem Engn & Energy, Zhengzhou 450001, Henan, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China
3.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
4.Henan Outstanding Foreign Scientists Workroom, Zhengzhou 450001, Peoples R China
推荐引用方式
GB/T 7714		 Bai, Jing,Zhang, Yang,Zhang, Xinghua,et al. Synthesis of High-Density Components of Jet Fuel from Lignin-Derived Aromatics via Alkylation and Subsequent Hydrodeoxygenation[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2021,9(20):7112-7119.
APA Bai, Jing,Zhang, Yang,Zhang, Xinghua,Wang, Chenguang,&Ma, Longlong.(2021).Synthesis of High-Density Components of Jet Fuel from Lignin-Derived Aromatics via Alkylation and Subsequent Hydrodeoxygenation.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,9(20),7112-7119.
MLA Bai, Jing,et al."Synthesis of High-Density Components of Jet Fuel from Lignin-Derived Aromatics via Alkylation and Subsequent Hydrodeoxygenation".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 9.20(2021):7112-7119.

入库方式： OAI收割

来源：广州能源研究所

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