An evaluation of the reactivity of synthetic Fe-Ni oxygen carriers: CO oxidation, H2O reforming, and toluene cracking
文献类型：期刊论文
| 作者 | Lin, Yan1,4,7,8; Zhang, Zhen1,2,7,8; Wang, Haitao1,7,8; Fang, Shiwen1,3,7,8; Huang, Zhen1,5,7,8; Chen, Tianju3,5; Wei, Guoqiang1,7,8; Zhao, Kun1,7,8 ; Zhao, Zengli1,7,8; Wu, Jinhu5
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| 刊名 | ENERGY CONVERSION AND MANAGEMENT
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| 出版日期 | 2021-07-15 |
| 卷号 | 240页码:12 |
| ISSN号 | 0196-8904 |
| 关键词 | Chemical looping Iron nickel oxide Distributed activation energy model of the time integral (DAEM-TI) CO oxidation H2O reforming Toluene cracking |
| DOI | 10.1016/j.enconman.2021.114263 |
| 通讯作者 | Huang, Zhen(huangzhen@ms.giec.ac.cn) |
| 英文摘要 | NiFe2O4 is an ideal oxygen carrier for the chemical looping process. This study focused on the evaluation of NiFe2O4 reactivity in relation to CO oxidation, H2O reforming and toluene (model tar) cracking. The NiFe2O4 was synthesized by the coprecipitation (CP), solid state (SS) and sol-gel (SG) methods for the TG and fixed bed experiments. We proposed a distributed activation energy model of the time integral, namely, DAEM-TI, for the evaluation of the reactivity of NiFe2O4 for CO oxidation (nonisothermal condition) and H2O reforming (isothermal condition). The goodness of the model fitting agreed well with the experimental data for CO oxidation (nonisothermal condition) but was slightly worse for H2O reforming (isothermal condition). The average activation energy, Emean, obtained by DAEM-TI was successfully used to determine the reactivity rank for different oxygen carriers. Emean analysis showed that the reactivity rank for CO oxidation was determined to be sample SG, sample SS and sample CP, and for H2O reforming, the rank determined to be sample CP, sample SG and sample SS. These results agreed well with TG analysis, and this finding will inspire the applications of the DAEM. In general, the sample SG showed better reactive performance for CO oxidation, H2O reforming and toluene cracking compared to the other samples. The inert support significantly increased the multiple redox cycle reactivity of NiFe2O4, and the improvement due to the inert support was ranked as follows: ZrO2 approximate to Al2O3 > TiO2(anatase) > TiO2(rutile) > SiO2. |
| WOS关键词 | CHEMICAL-LOOPING GASIFICATION ; ACTIVATION-ENERGY MODEL ; HYDROGEN-PRODUCTION ; NICKEL FERRITE ; PYROLYSIS KINETICS ; BIOMASS ; NIFE2O4 ; METHANE ; OXIDES ; TAR |
| 资助项目 | Guangdong Basic and Applied Basic Research Foundation[2019B1515120022] ; Guangdong Basic and Applied Basic Research Foundation[2019A1515110828] ; Guangdong Basic and Applied Basic Research Foundation[2020A1515110138] ; Guangdong Basic and Applied Basic Research Foundation[2021A1515010459] ; National Natural Science Foundation of China[52076209] ; National Natural Science Foundation of China[51776210] ; National Natural Science Foundation of China[52006224] ; National Key Research and Development Program of China[2020YFC1908901] ; National Key Research and Development Program of China[2018YFB0605405] ; DNL Cooperation Fund, CAS[DNL180205] ; Youth Innovation Promotion Association, CAS[2018384] ; Pearl River S&T Nova Program of Guangzhou[201906010092] ; CAS Key Laboratory of Renewable Energy[E029kf0801] ; CAS Key Laboratory of Renewable Energy[2020000022] ; Foundation of Key Laboratory of Biofuels, Qingdao Institute of Bioenergy and Bioprocess Technology, CAS[CASKLB201810] |
| WOS研究方向 | Thermodynamics ; Energy & Fuels ; Mechanics |
| 语种 | 英语 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| WOS记录号 | WOS:000659044100005 |
| 资助机构 | Guangdong Basic and Applied Basic Research Foundation ; National Natural Science Foundation of China ; National Key Research and Development Program of China ; DNL Cooperation Fund, CAS ; Youth Innovation Promotion Association, CAS ; Pearl River S&T Nova Program of Guangzhou ; CAS Key Laboratory of Renewable Energy ; Foundation of Key Laboratory of Biofuels, Qingdao Institute of Bioenergy and Bioprocess Technology, CAS |
| 源URL | [http://ir.giec.ac.cn/handle/344007/33340]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Huang, Zhen |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.Guangzhou Univ, Sch Mech & Elect Engn, Guangzhou 510640, Peoples R China 3.Zhongkai Univ Agr & Engn, Coll Mech & Elect Engn, Guangzhou 510225, Peoples R China 4.State Key Lab High Efficiency Utilizat Coal & Gre, Yinchuan 750021, Ningxia, Peoples R China 5.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, Qingdao 266101, Peoples R China 6.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China 7.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 8.Guangdong Prov Key Lab New Renewable Energy Res &, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lin, Yan,Zhang, Zhen,Wang, Haitao,et al. An evaluation of the reactivity of synthetic Fe-Ni oxygen carriers: CO oxidation, H2O reforming, and toluene cracking[J]. ENERGY CONVERSION AND MANAGEMENT,2021,240:12. |
| APA | Lin, Yan.,Zhang, Zhen.,Wang, Haitao.,Fang, Shiwen.,Huang, Zhen.,...&Li, Haibin.(2021).An evaluation of the reactivity of synthetic Fe-Ni oxygen carriers: CO oxidation, H2O reforming, and toluene cracking.ENERGY CONVERSION AND MANAGEMENT,240,12. |
| MLA | Lin, Yan,et al."An evaluation of the reactivity of synthetic Fe-Ni oxygen carriers: CO oxidation, H2O reforming, and toluene cracking".ENERGY CONVERSION AND MANAGEMENT 240(2021):12. |
入库方式： OAI收割
来源：广州能源研究所
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