Highly active and durable Ca-based solid base catalyst for biodiesel production
文献类型：期刊论文
| 作者 | Liu, Xiaochun1,3,4,5; Xing, Shiyou1,4,5; Yang, Lingmei1,4,5 ; Fu, Junying1,3,4,5; Lv, Pengmei1,4,5; Zhang, Xufeng1,2,4,5; Li, Ming1,4,5; Wang, Zhongming1,4,5
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| 刊名 | FUEL
 |
| 出版日期 | 2021-10-15 |
| 卷号 | 302页码:11 |
| ISSN号 | 0016-2361 |
| DOI | 10.1016/j.fuel.2021.121094 |
| 通讯作者 | Fu, Junying(fujy@ms.giec.ac.cn) ; Lv, Pengmei() |
| 英文摘要 | Calcium-based (Ca-based) oxides are promising candidates to replace sodium or potassium hydroxide as base catalysts in transesterification for biodiesel production, owe to their high activity and recyclability. However, their readily leaching in the reaction process is the main reason for its low reusability. This problem has long been the bottleneck of heterogeneous catalytic transesterification for biodiesel production. To solve this problem, we employed a solid-state synthesis approach to fabricate the Ca-based solid base catalyst, which showed extraordinarily high activity and stability for biodiesel synthesis. The catalyst, named NCS, could achieve up to 98.0% biodiesel (fatty acid methyl esters, FAMEs) yield in 1 h at 90 degrees C with 5 wt% of catalyst loading. The catalyst can be reused 26 times with a biodiesel yield of at least 90.0%. With thorough characterization, we found that the extraordinary performance of the catalyst owes to the strong basic sites and its anti-carbonation ability. The strong basic sites, formed by the coordination between O, Na, Si, and Ca, can also moderate the leaching of Ca-related basic sites into the reaction medium. Performance reduction of NCS could be attributed to the shift of strong basic sites to weaker ones without significant loss of total basic sites. Above all, we believe that the NCS catalyst is a promising catalyst for large-scale biodiesel production. |
| WOS关键词 | SOYBEAN OIL ; CALCIUM-OXIDE ; HETEROGENEOUS CATALYSTS ; CANOLA OIL ; TRANSESTERIFICATION ; CONVERSION ; SILICA ; SITES |
| 资助项目 | National Key R&D Program of China[2019YFB1504003] |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000675732000009 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | National Key R&D Program of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/33508]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Fu, Junying; Lv, Pengmei |
| 作者单位 | 1.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 2.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Jiangsu, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 5.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Xiaochun,Xing, Shiyou,Yang, Lingmei,et al. Highly active and durable Ca-based solid base catalyst for biodiesel production[J]. FUEL,2021,302:11. |
| APA | Liu, Xiaochun.,Xing, Shiyou.,Yang, Lingmei.,Fu, Junying.,Lv, Pengmei.,...&Wang, Zhongming.(2021).Highly active and durable Ca-based solid base catalyst for biodiesel production.FUEL,302,11. |
| MLA | Liu, Xiaochun,et al."Highly active and durable Ca-based solid base catalyst for biodiesel production".FUEL 302(2021):11. |
入库方式： OAI收割
来源：广州能源研究所
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