Synergistic effects for fast co-pyrolysis of strong-acid cation exchange resin and cellulose using Py-GC/MS
文献类型：期刊论文
| 作者 | Zhang, Jun1,3,4,5; Li, Chengyu1,2,3,4,5; Gu, Jing1,3,4,5; Yuan, Haoran1,3,4,5 ; Chen, Yong1,3,4,5
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| 刊名 | FUEL
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| 出版日期 | 2021-10-15 |
| 卷号 | 302页码:6 |
| ISSN号 | 0016-2361 |
| DOI | 10.1016/j.fuel.2021.121232 |
| 通讯作者 | Yuan, Haoran(yuanhr@ms.giec.ac.cn) |
| 英文摘要 | This study aimed to investigate the co-pyrolysis characteristics of strong-acid cation exchange resin (Amberlyst15, denoted as A15) and cellulose (CE), in which the existing synergistic interaction effects were uncovered. Crucial variables including pyrolytic temperature, A15-to-CE mass ratio and heating rate were taken into consideration. The levoglucosenone (LGO) production from CE and inorganic sulfur-containing species release from functional sulfonic acid groups of A15 were enhanced in a temperature range of below 400 degrees C. In this regard, the LGO yield achieved approximately 7 wt% at 300 degrees C with A15-to-CE mass ratio of 1:1. Relatively, elevating the temperature and heating rate accelerated the A15 self-decomposition and small molecule fragments restructuring to give much more monocyclic and polycyclic aromatics. Noticeably, organic sulfur-containing compounds also were produced in an unignorable amount of 8.2% under preset conditions of pyrolytic temperature of 700 degrees C and heating rate of 20,000 degrees C/s. The plausible pathway for the co-pyrolysis transformation of A15 and CE was also proposed on the basis of experimental results. The present work will provide a probable and feasible strategy for the high-value utilization of biomass and waste ion-exchange resins, particularly in the aspect of the generation of certain chemicals. |
| WOS关键词 | CATALYTIC FAST PYROLYSIS ; BIOMASS ; HZSM-5 ; ZSM-5 |
| 资助项目 | National Key R&D Program of China[2018YFC1901200] ; National Natural Science Foundation of China[51976222] ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou)[GML2019ZD0101] ; State Key Laboratory of Clean Energy Utilization[ZJUCEU2020023] ; Science and Technology Planning Project of Guangzhou[201904010351] |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCI LTD |
| WOS记录号 | WOS:000675732000012 |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) ; State Key Laboratory of Clean Energy Utilization ; Science and Technology Planning Project of Guangzhou |
| 源URL | [http://ir.giec.ac.cn/handle/344007/33511]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Yuan, Haoran |
| 作者单位 | 1.Southern Marine Sci & Engn Guangdong Lab Guangzho, Guangzhou 511458, Peoples R China 2.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 5.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Jun,Li, Chengyu,Gu, Jing,et al. Synergistic effects for fast co-pyrolysis of strong-acid cation exchange resin and cellulose using Py-GC/MS[J]. FUEL,2021,302:6. |
| APA | Zhang, Jun,Li, Chengyu,Gu, Jing,Yuan, Haoran,&Chen, Yong.(2021).Synergistic effects for fast co-pyrolysis of strong-acid cation exchange resin and cellulose using Py-GC/MS.FUEL,302,6. |
| MLA | Zhang, Jun,et al."Synergistic effects for fast co-pyrolysis of strong-acid cation exchange resin and cellulose using Py-GC/MS".FUEL 302(2021):6. |
入库方式： OAI收割
来源：广州能源研究所
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