Co-pyrolysis of pine sawdust with aluminum dross for immobilization of heavy metal and enhancing hydrogen generation
文献类型：期刊论文
| 作者 | Liu, Peng2,3; Liu, Li3; Zhou, Zhengzhong3; Li, Yanling3; Yuan, Haoran1,3 ; Huhetaoli2,3; Lei, Tingzhou3
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| 刊名 | FUEL
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| 出版日期 | 2021-12-01 |
| 卷号 | 305页码:8 |
| 关键词 | Aluminum dross Biomass pyrolysis Intermediate hybrid Hydrogen generation Carbon structure |
| ISSN号 | 0016-2361 |
| DOI | 10.1016/j.fuel.2021.121597 |
| 通讯作者 | Lei, Tingzhou(china_newenergy@163.com) |
| 英文摘要 | Co-pyrolysis of pine sawdust with aluminum dross (AD) for harvesting energy product and safely treated ADbiochar composite was investigated in this work. The catalytic pyrolysis experiment was carried out in a fixed bed reactor. The pyrolysis products were analyzed by gas chromatography (GC), gas chromatography coupled with a mass spectrometer (GC-MS), and solid C-13 Nuclear Magnetic Resonance (C-13 NMR). The results show that the heavy metals, such as Cu, were immobilized by organic metal-chelating structures as carbon-oxygen-metal (C-O-M) bonds in the AD-biochar composite. In addition, the hydrogen yield from catalytic pyrolysis of pine on AD reaches 131.86 ml/g, significantly higher than the 98.97 ml/g from pure pine pyrolysis. The enhanced hydrogen production is elaborated by the intermediate hybrid mechanism with formation of C-O-M intermediates between the metallic oxides in AD and the oxygen containing functional groups in biomass. Meanwhile, the CO2 yield decreases from 23.68 ml/g to 16.41 ml/g while the CO yield reduces from 49.72 ml/g to 46.85 ml/g. These results may guide to a new exploration on simultaneous treatment of hazardous industrial wastes and utilization of biomass. |
| WOS关键词 | INCINERATION FLY-ASH ; SEWAGE-SLUDGE ; BIOMASS PYROLYSIS ; HAZARDOUS-WASTE ; GASIFICATION CATALYST ; BIO-OIL ; CARBON ; REMOVAL ; CHAR ; TAR |
| 资助项目 | National Key R&D Program of China[2018YFC1901203] ; Natural Science Foundation of China[51906021] ; Natural Science Foundation of Colleges in Jiangsu Province[19KJB480005] ; Changzhou Applied Basic Research Plan[CJ20190081] ; Energy Revolution Strategy Research of Henan Province |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000702825400001 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | National Key R&D Program of China ; Natural Science Foundation of China ; Natural Science Foundation of Colleges in Jiangsu Province ; Changzhou Applied Basic Research Plan ; Energy Revolution Strategy Research of Henan Province |
| 源URL | [http://ir.giec.ac.cn/handle/344007/34792]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Lei, Tingzhou |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou, Peoples R China 2.Nanjing Univ Technol, Jiangsu Key Lab Proc Enhancement & New Energy Equ, Nanjing, Peoples R China 3.Changzhou Univ, Natl Local Joint Engn Res Ctr Biomass Refining &, Inst Urban & Rural Min, Changzhou, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Peng,Liu, Li,Zhou, Zhengzhong,et al. Co-pyrolysis of pine sawdust with aluminum dross for immobilization of heavy metal and enhancing hydrogen generation[J]. FUEL,2021,305:8. |
| APA | Liu, Peng.,Liu, Li.,Zhou, Zhengzhong.,Li, Yanling.,Yuan, Haoran.,...&Lei, Tingzhou.(2021).Co-pyrolysis of pine sawdust with aluminum dross for immobilization of heavy metal and enhancing hydrogen generation.FUEL,305,8. |
| MLA | Liu, Peng,et al."Co-pyrolysis of pine sawdust with aluminum dross for immobilization of heavy metal and enhancing hydrogen generation".FUEL 305(2021):8. |
入库方式： OAI收割
来源：广州能源研究所
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