Hydrodeoxygenation of lignin-derived phenolic compounds over Ru/ TiO2-CeO2 catalyst prepared by photochemical reduction method
文献类型：期刊论文
| 作者 | Shu, Riyang1,2; Zhong, Zhuojie2; You, Hongyun2; Tian, Zhipeng2; Chen, Ying2; Ma, Longlong1
|
| 刊名 | JOURNAL OF THE ENERGY INSTITUTE
 |
| 出版日期 | 2021-12-01 |
| 卷号 | 99页码:1-8 |
| 关键词 | HDO Phenolic compounds Acid sites CeO2 Oxygen vacancy |
| ISSN号 | 1743-9671 |
| DOI | 10.1016/j.joei.2021.07.012 |
| 通讯作者 | Chen, Ying(chenying@gdut.edu.cn) ; Ma, Longlong(mall@ms.giec.ac.cn) |
| 英文摘要 | Hydrodeoxygenation (HDO) is an important pathway for lignin-oil upgradation to produce high quality liquid fuels, in which the high-active catalyst is the key point to achieve a high HDO efficiency. In this study, Ru/TiO2, Ru/CeO2 and Ru/TiO2-CeO2 catalysts were synthesized by a novel photochemical method with a high Ru dispersion and used for the HDO of lignin-derived phenolic compounds. Among these three catalysts, Ru/ TiO2-CeO2 showed a better performance than Ru/TiO2 and Ru/CeO2. And guaiacol was transformed into cyclohexane with conversion and product selectivity close to 100 % at 230 degrees C under 1 MPa hydrogen atmosphere. Ru/TiO2-CeO2 took the advantages of Ru/TiO2 and Ru/CeO2, namely high Ru metal dispersion, plenty of medium strength acid sites and abundance of oxygen vacancy, which promoted the guaiacol adsorption and the HDO catalytic activity. Moreover, Ru/TiO2-CeO2 catalyst showed an effective upgrading of other lignin-derived phenolic compounds. And the lignin-oil also enabled to be upgraded efficiently, producing a high content of hydrocarbons and alkylphenols. |
| WOS关键词 | BIO-OIL ; BIOMASS ; DEPOLYMERIZATION ; HYDROGENOLYSIS ; PERFORMANCE ; PYROLYSIS ; OXIDATION ; SPHERES ; ENERGY |
| 资助项目 | CAS Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion[E029kf0101] ; Guangdong Special Support Program[2017TX04N371] |
| WOS研究方向 | Energy & Fuels |
| 语种 | 英语 |
| WOS记录号 | WOS:000703516200001 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | CAS Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion ; Guangdong Special Support Program |
| 源URL | [http://ir.giec.ac.cn/handle/344007/34804]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Chen, Ying; Ma, Longlong |
| 作者单位 | 1.Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 2.Guangdong Univ Technol, Sch Mat & Energy, Guangdong Prov Key Lab Funct Soft Condensed Matte, Guangzhou 510006, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shu, Riyang,Zhong, Zhuojie,You, Hongyun,et al. Hydrodeoxygenation of lignin-derived phenolic compounds over Ru/ TiO2-CeO2 catalyst prepared by photochemical reduction method[J]. JOURNAL OF THE ENERGY INSTITUTE,2021,99:1-8. |
| APA | Shu, Riyang,Zhong, Zhuojie,You, Hongyun,Tian, Zhipeng,Chen, Ying,&Ma, Longlong.(2021).Hydrodeoxygenation of lignin-derived phenolic compounds over Ru/ TiO2-CeO2 catalyst prepared by photochemical reduction method.JOURNAL OF THE ENERGY INSTITUTE,99,1-8. |
| MLA | Shu, Riyang,et al."Hydrodeoxygenation of lignin-derived phenolic compounds over Ru/ TiO2-CeO2 catalyst prepared by photochemical reduction method".JOURNAL OF THE ENERGY INSTITUTE 99(2021):1-8. |
入库方式： OAI收割
来源：广州能源研究所
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