Reactivity investigation on chemical looping gasification of coal with Iron-Manganese based oxygen carrier
文献类型：期刊论文
| 作者 | Zhou, Huan1,2,4; Wei, Guoqiang4; Yi, Qun2,3; Zhang, Zheming1; Zhao, Yingjie2; Zhang, Yuke2; Huang, Zhen4; Zheng, Anqing4 ; Zhao, Kun4; Zhao, Zengli4
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| 刊名 | FUEL
 |
| 出版日期 | 2022 |
| 卷号 | 307页码:14 |
| ISSN号 | 0016-2361 |
| 关键词 | Chemical looping gasification (CLG) Iron-manganese oxygen carrier (OC) Gasification characteristics Oxygen transfer |
| DOI | 10.1016/j.fuel.2021.121772 |
| 通讯作者 | Yi, Qun(yiqun@tyut.edu.cn) ; Huang, Zhen(huangzhen@ms.giec.ac.cn) |
| 英文摘要 | Chemical looping gasification (CLG) of Yunnan lignite with Fe-Mn mixed oxygen carriers (OCs) was performed to achieve high purity synthesis gas and reduce pollutant emissions. The Fe-Mn composite OCs presented the characteristics of oxygen decoupling, and there is a synergistic effect between the active components using various analytical methods. The maximum syngas yield (0.054 mol/g) and the maximum carbon conversion rate (62.9%) were achieved under the following conditions; temperature at 900 degrees C, steam flow rate at 0.045 ml/min and O/C ratio equal to 1. The OC acts as both oxygen source and catalyst in gasification reaction process, after studying the gasification reaction characteristics between the OC and the model compound. The oxygen transport mechanism and phase evolution law of the OC was revealed by conducting XRD and XPS tests. The migration of lattice oxygen of the OC in CLG transferred from bulk phase to surface phase with the migration pathway of oxygen species OI -> OII -> OIII, and the OC phase underwent the reduction process of (Mn, Fe)(2)O-3 -> (FeO)(0.664)(MnO)(0.336) -> Fe/MnO. The reactivity performance of OCs remained stable after 20-cycle redox experiments, indicating that the Fe-Mn OC was a good candidate OC for the CLG process. |
| WOS关键词 | SYNGAS PRODUCTION ; COMBUSTION ; PROGRESS ; OXIDES ; PERFORMANCE ; CONVERSION ; METHANE |
| 资助项目 | National Key R&D Program of China[2018YFB0605404] ; National Natural Science Foundation of China[51776133] ; National Natural Science Foundation of China[U1810125] ; National Natural Science Foundation of China[51976226] ; Key R&D Program of Shanxi Province[201903D121031] ; Chinese Academy of Sciences[DNL180205] ; Natural Science Foundation of Guangdong Province[2018A0303130012] ; Foundation of State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering[2020-KF-04] |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCI LTD |
| WOS记录号 | WOS:000703346000008 |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China ; Key R&D Program of Shanxi Province ; Chinese Academy of Sciences ; Natural Science Foundation of Guangdong Province ; Foundation of State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering |
| 源URL | [http://ir.giec.ac.cn/handle/344007/34810]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Yi, Qun; Huang, Zhen |
| 作者单位 | 1.Beijing Inst Technol, Shenzhen Automot Res Inst, Shenzhen, Peoples R China 2.Taiyuan Univ Technol, Coll Environm Sci & Engn, Taiyuan 030024, Peoples R China 3.Wuhan Inst Technol, Key Lab Green Chem Engn Proc, Minist Educ, Wuhan 430205, Peoples R China 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, CAS, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Huan,Wei, Guoqiang,Yi, Qun,et al. Reactivity investigation on chemical looping gasification of coal with Iron-Manganese based oxygen carrier[J]. FUEL,2022,307:14. |
| APA | Zhou, Huan.,Wei, Guoqiang.,Yi, Qun.,Zhang, Zheming.,Zhao, Yingjie.,...&Zhao, Zengli.(2022).Reactivity investigation on chemical looping gasification of coal with Iron-Manganese based oxygen carrier.FUEL,307,14. |
| MLA | Zhou, Huan,et al."Reactivity investigation on chemical looping gasification of coal with Iron-Manganese based oxygen carrier".FUEL 307(2022):14. |
入库方式： OAI收割
来源：广州能源研究所
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