中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
首页 机构 成果 学者
  
  1. CAS IR Grid
  2. 广州能源研究所
  3. 中国科学院广州能源研究所
Boron doped magnetic catalysts for selective transfer hydrogenation of furfural into furfuryl alcohol

文献类型：期刊论文

作者Li, Danni1,2,4,5; Zhang, Jun1,2,3,4; Liu, Ying5; Yuan, Haoran1,2,3,4; Chen, Yong1,2,3,4
刊名CHEMICAL ENGINEERING SCIENCE
出版日期2021-01-16
卷号229页码:12
ISSN号0009-2509
关键词Magnetic catalysts Transfer hydrogenation Furfural Furfuryl alcohol Activation energy
DOI10.1016/j.ces.2020.116075
通讯作者Liu, Ying(amyliu@scut.edu.cn) ; Yuan, Haoran(yuanhr@ms.giec.ac.cn)
英文摘要A series of boron doped magnetic zirconium catalysts were developed for the selective transfer hydrogenation of biomass-derived furfural (FFR) into furfuryl alcohol (FA) using 2-propanol as hydrogen source and solvent. Full characterizations with XRD, SEM, TG, Py-IR, NH3-TPD, and CO2-TPD techniques were undertaken to uncover structural properties of magnetic catalysts. Boron doped magnetic zirconium catalysts endowing with adjustable acid-base sites exhibited excellent performance as well as good regenerability in the transfer hydrogenation of FFR, where almost 100% FA yield was achieved in the presence of 2-propanol and the catalyst still sustained good activity after being used five times. Suitable acidity/ basicity ratio of 3.8 similar to 4.0 apparently benefited the selective production of FA. Gratifyingly, the activation energy for FA formation over Zr1B3FeO was as low as 48.3 kJ/mol. In addition, plausible reaction mechanism involving two H-transfer paths for transfer hydrogenation of FFR into FA under the catalysis of active Zr/B species was proposed. (c) 2020 Elsevier Ltd. All rights reserved.
WOS关键词PONNDORF-VERLEY REDUCTION ; EFFICIENT SYNTHESIS ; BIOMASS ; ACID ; CONVERSION ; ZIRCONIA ; COPPER ; VALEROLACTONE ; NANOPARTICLES ; MECHANISM
资助项目National Key R&D Program of China[2018YFC1901200] ; National Natural Science Foundation of China[51976222] ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou)[GML2019ZD0101] ; Natural Science Foundation of Guangdong Province, China[2018A030313856]
WOS研究方向Engineering
语种英语
出版者PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号WOS:000583263000008
资助机构National Key R&D Program of China ; National Natural Science Foundation of China ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) ; Natural Science Foundation of Guangdong Province, China
源URL[http://ir.giec.ac.cn/handle/344007/34859]  
专题中国科学院广州能源研究所
通讯作者Liu, Ying; Yuan, Haoran
作者单位1.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China
2.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China
3.Southern Marine Sci & Engn Guangdong Lab, Guangzhou 511458, Peoples R China
4.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
5.South China Univ Technol, State Key Lab Pulp & Paper Engn, Sch Light Ind & Engn, Guangzhou 510640, Peoples R China
推荐引用方式
GB/T 7714		 Li, Danni,Zhang, Jun,Liu, Ying,et al. Boron doped magnetic catalysts for selective transfer hydrogenation of furfural into furfuryl alcohol[J]. CHEMICAL ENGINEERING SCIENCE,2021,229:12.
APA Li, Danni,Zhang, Jun,Liu, Ying,Yuan, Haoran,&Chen, Yong.(2021).Boron doped magnetic catalysts for selective transfer hydrogenation of furfural into furfuryl alcohol.CHEMICAL ENGINEERING SCIENCE,229,12.
MLA Li, Danni,et al."Boron doped magnetic catalysts for selective transfer hydrogenation of furfural into furfuryl alcohol".CHEMICAL ENGINEERING SCIENCE 229(2021):12.

入库方式： OAI收割

来源：广州能源研究所

浏览0
下载0
收藏0
其他版本

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。