Biotransformation of 6:2 fluorotelomer alcohol by the whole soybean (Glycine max L. Merrill) seedlings
文献类型：期刊论文
| 作者 | Zhang, Hongna; Wen, Bei; Huang, Honglin ; Wang, Sen; Cai, Zongwei; Zhang, Shuzhen
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| 刊名 | ENVIRONMENTAL POLLUTION
 |
| 出版日期 | 2020-02 |
| 卷号 | 257页码:1-11 |
| 关键词 | 6:2 Fluorotelomer alcohol Perfluorocarboxylic acid Biotransformation GSH-Conjugated metabolite Soybean |
| ISSN号 | 0269-7491 |
| 英文摘要 | Fluorotelomer alcohols (FTOHs) are important precursors of perfluorocarboxylic acids (PFCAs) in the environment and biota. With the growing application of 6:2 FTOH [F(CF2)(6)CH2CH2OH] in product formulation, it is becoming increasingly urgent to investigate its biological fates in different species. In this study, biotransformation of 6:2 FTOH by young soybean plants (Glycine max L Merrill) were investigated using hydroponic experiments. During the 144 h-exposure, 6:2 FTCA [F(CF2)(6)CH2COOH], 6:2 FTUCA [F(CF2)(5)CF=CHCOOH], 5:3 FTUCA [F(CF2)(5)CH=CHCOOH], 5:3 FTCA [F(CF2)(5)CH2CH2COOH}, PFHxA [F(CF2)(5)COOH] and PFPeA [F(CF2)(4)COOH] were phase I metabolites in soybean. At the end of exposure, 5:3 FTCA (5.08 mol%), PFHxA (234 mol%) and PFPeA (0.58 mol%) were three main metabolites in soybean-solution system. 5:3 FTCA was predominant in soybean roots and stems, while PFHxA was the most abundant product in leaves. PFBA [F(CF2)(3)COOH] and 4:3 FTCA [F(CF2)(4)CH2CH2COOH] detected in the hydroponic solution most-likely came from the transformation of 5:3 FTCA by root-associated microbes. Moreover, phase II metabolites of 6:2 FTOH were identified and monitored in soybean tissues. Alcohol dehydrogenase, aldehyde dehydrogenase and glutathione S-transferase were found to participate in 6:2 FTOH metabolism. Based on the phase I and phase II metabolism of 6:2 FTOH in soybean, this study for the first time provides evidences for the transformation pathways of 6:2 FTOH in plants. (C) 2019 Published by Elsevier Ltd. |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/44621]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Zhang, Hongna,Wen, Bei,Huang, Honglin,et al. Biotransformation of 6:2 fluorotelomer alcohol by the whole soybean (Glycine max L. Merrill) seedlings[J]. ENVIRONMENTAL POLLUTION,2020,257:1-11. |
| APA | Zhang, Hongna,Wen, Bei,Huang, Honglin,Wang, Sen,Cai, Zongwei,&Zhang, Shuzhen.(2020).Biotransformation of 6:2 fluorotelomer alcohol by the whole soybean (Glycine max L. Merrill) seedlings.ENVIRONMENTAL POLLUTION,257,1-11. |
| MLA | Zhang, Hongna,et al."Biotransformation of 6:2 fluorotelomer alcohol by the whole soybean (Glycine max L. Merrill) seedlings".ENVIRONMENTAL POLLUTION 257(2020):1-11. |
入库方式： OAI收割
来源：生态环境研究中心
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