Introduction of protonic potential of Bronsted - Lowry acids and bases to the quantification of the energy of proton translocation and elucidation of oxidative phosphorylation
文献类型：期刊论文
| 作者 | Wang, Yaotian; Wang, Jianguo; Pang, Junjie; Zhang, Lijuan; Xu, Wenwen; Shao, Cuimin |
| 刊名 | JOURNAL OF ELECTROANALYTICAL CHEMISTRY
 |
| 出版日期 | 2020-03-01 |
| 卷号 | 860页码:1-18 |
| 关键词 | ATP Hydroquinone Oxidative phosphorylation Protonic potential Quinone Proton transfer |
| ISSN号 | 1572-6657 |
| 英文摘要 | ATP synthesis in mitochondria is driven by the pH gradient between lipid membranes, and a proton-motive force (PMF) forms along the respiratory electron-transport chain. The reasons for these phenomena remain unclear. In an unbuffered quinone solution, acids induce the formation of new cathodic peaks, whose peak potential is dependent on their pK(a). Thus, the protons of acids have a potential defined as protonic potential. Herein, the energy of proton translocation was easily quantified by protonic potential. We observed that the redox potential of chemical reactions can be transformed into the protonic potential of Bronsted - Lowry acids and bases in an unbuffered solution. We postulated that in the mitochondrial membrane, the redox potential of the respiratory chain can be transformed to protonic potential and that the PMF originates from the protonic potential difference between compounds. Ultimately, the protonic potential energy derived from redox reactions was stored in the ATP. (C) 2020 Elsevier B.V. All rights reserved. |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/44717]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Wang, Yaotian,Wang, Jianguo,Pang, Junjie,et al. Introduction of protonic potential of Bronsted - Lowry acids and bases to the quantification of the energy of proton translocation and elucidation of oxidative phosphorylation[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY,2020,860:1-18. |
| APA | Wang, Yaotian,Wang, Jianguo,Pang, Junjie,Zhang, Lijuan,Xu, Wenwen,&Shao, Cuimin.(2020).Introduction of protonic potential of Bronsted - Lowry acids and bases to the quantification of the energy of proton translocation and elucidation of oxidative phosphorylation.JOURNAL OF ELECTROANALYTICAL CHEMISTRY,860,1-18. |
| MLA | Wang, Yaotian,et al."Introduction of protonic potential of Bronsted - Lowry acids and bases to the quantification of the energy of proton translocation and elucidation of oxidative phosphorylation".JOURNAL OF ELECTROANALYTICAL CHEMISTRY 860(2020):1-18. |
入库方式： OAI收割
来源：生态环境研究中心
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