Sorption kinetics of parent and substituted PAHs for low-density polyethylene (LDPE): Determining their partition coefficients between LDPE and water (K-LDPE) for passive sampling
文献类型：期刊论文
| 作者 | Lei, Pei; Zhu, Jinjie; Pan, Ke; Zhang, Hong
|
| 刊名 | JOURNAL OF ENVIRONMENTAL SCIENCES
 |
| 出版日期 | 2020-01 |
| 卷号 | 87页码:349-360 |
| 关键词 | Low-density polyethylene (LDPE) PAHs Substituted PAHs (SPAHs) Freely dissolved concentrations Passive sampling |
| ISSN号 | 1001-0742 |
| 英文摘要 | Low-density polyethylene (LDPE) has been widely used as a sorbent for passive sampling of hydrophobic organic contaminants (HOCs) in aquatic environments. However, it has seen only limited application in passive sampling for measurement of freely dissolved concentrations of parent and substituted PAHs (SPAHs), which are known to be toxic, mutagenic and carcinogenic. Here, the 16 priority PAHs and some typical PAHs were selected as target compounds and were simultaneously determined by gas chromatography-mass spectrometer (GC-MS). Some batch experiments were conducted in the laboratory to explore the adsorption kinetics of the target compounds in LDPE membranes. The results showed that both PAHs and SPAHs could reach equilibrium status within 19-38 days in sorption kinetic experiments. The coefficients of partitioning between LDPE film (50 mu m thickness) and water (K-LDPE) for the 16 priority PAHs were in good agreement with previously reported values, and the values of K-LDPE for the 9 SPAHs are reported in this study for the first time. Significant linear relationships were observed, i.e., log K-LDPE = 0.705 x log K-OW + 1.534 for PAHs (R-2 = 0.8361, p < 0.001) and log K-LDPE = 0.458 x log K-OW + 3.092 for SPAHs (R-2 = 0.5609, p = 0.0077). The selected LDPE film was also proven to meet the condition of zero sink for the selected target compounds. These results could provide basic support for the configuration and in situ application of passive samplers. (c) 2019 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V. |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/44994]  |
| 专题 | 生态环境研究中心_环境水质学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Lei, Pei,Zhu, Jinjie,Pan, Ke,et al. Sorption kinetics of parent and substituted PAHs for low-density polyethylene (LDPE): Determining their partition coefficients between LDPE and water (K-LDPE) for passive sampling[J]. JOURNAL OF ENVIRONMENTAL SCIENCES,2020,87:349-360. |
| APA | Lei, Pei,Zhu, Jinjie,Pan, Ke,&Zhang, Hong.(2020).Sorption kinetics of parent and substituted PAHs for low-density polyethylene (LDPE): Determining their partition coefficients between LDPE and water (K-LDPE) for passive sampling.JOURNAL OF ENVIRONMENTAL SCIENCES,87,349-360. |
| MLA | Lei, Pei,et al."Sorption kinetics of parent and substituted PAHs for low-density polyethylene (LDPE): Determining their partition coefficients between LDPE and water (K-LDPE) for passive sampling".JOURNAL OF ENVIRONMENTAL SCIENCES 87(2020):349-360. |
入库方式： OAI收割
来源：生态环境研究中心
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