A superior Fe-V-Ti catalyst with high activity and SO2 resistance for the selective catalytic reduction of NOx with NH3
文献类型：期刊论文
| 作者 | Zhu, Na; Shan, Wenpo; Lian, Zhihua; Zhang, Yan; Liu, Kuo; He, Hong
|
| 刊名 | JOURNAL OF HAZARDOUS MATERIALS
 |
| 出版日期 | 2020-01-15 |
| 卷号 | 382页码:1-10 |
| 关键词 | Fe-V-Ti catalysts NH3-SCR SO2 resistance Reaction mechanism |
| ISSN号 | 0304-3894 |
| 英文摘要 | A series of Fe-V-Ti oxide catalysts were prepared by a co-precipitation method, among which the Fe0.1V0.1TiOx catalyst showed the optimal NH3-SCR performance and excellent SO2 resistance. Fe0.1V0.1TiOx achieved > 90% NOx conversion at 225-450 degrees C under a GHSV of 200,000 h(-1). When introducing SO2 and H2O to the SCR reaction for 24 h, the NOx conversion maintained a level above 93% at 250 degrees C. The Raman and Mossbauer spectra showed that FeVO4 and Fe2O3 coexisted on the surface of TiO2. In Fe-V-Ti catalysts, the charge interaction between Fe2O3 and FeVO4 as well as the electronic inductive effect between Fe and V species resulted in the improvement of SCR activity and N-2 selectivity at high temperatures. The NH3-SCR process on the Fe0.1V0.1TiOx catalyst mainly followed the Eley-Rideal (E-R) reaction mechanism with gaseous NO reacting with adsorbed NH3 adsorbed species. |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/44534]  |
| 专题 | 生态环境研究中心_大气污染控制中心 |
| 推荐引用方式 GB/T 7714 | Zhu, Na,Shan, Wenpo,Lian, Zhihua,et al. A superior Fe-V-Ti catalyst with high activity and SO2 resistance for the selective catalytic reduction of NOx with NH3[J]. JOURNAL OF HAZARDOUS MATERIALS,2020,382:1-10. |
| APA | Zhu, Na,Shan, Wenpo,Lian, Zhihua,Zhang, Yan,Liu, Kuo,&He, Hong.(2020).A superior Fe-V-Ti catalyst with high activity and SO2 resistance for the selective catalytic reduction of NOx with NH3.JOURNAL OF HAZARDOUS MATERIALS,382,1-10. |
| MLA | Zhu, Na,et al."A superior Fe-V-Ti catalyst with high activity and SO2 resistance for the selective catalytic reduction of NOx with NH3".JOURNAL OF HAZARDOUS MATERIALS 382(2020):1-10. |
入库方式： OAI收割
来源：生态环境研究中心
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