Constructing zwitterionic polymer brush layer to enhance gravity-driven membrane performance by governing biofilm formation
文献类型：期刊论文
| 作者 | Liu, Caihong; Song, Dan; Zhang, Wenjuan; He, Qiang; Huangfu, Xiaoliu; Sun, Shaofang; Sun, Zhiqiang; Cheng, Wei; Ma, Jun |
| 刊名 | WATER RESEARCH
 |
| 出版日期 | 2020 |
| 卷号 | 168页码:1-26 |
| 关键词 | Gravity-driven membrane Zwitterionic polymers Antifouling Flux stabilization Biofilm |
| ISSN号 | 0043-1354 |
| 英文摘要 | In this study, zwitterionic polymer brushes with controlled architecture were grafted on the surface of gravity-driven membrane (GDM) via surface-initiated reaction to impart antifouling property. A variety of membrane characterization techniques were conducted to demonstrate the successful functionalization of zwitterionic polymers on PVDF hollow fiber membrane. The membrane underwent 90 min of reaction time possessing strong hydrophilicity and high permeability was determined as the optimal modified membrane. Long-term GDM dynamic fouling experiments operated for 30 days using sewage wastewater as feed solution indicated zwitterionic polymer modified membrane exhibit excellent membrane fouling resistance thus enhanced stable flux. Confocal laser scanning microscopy (CLSM) imaging implied that zwitterionic polymer modification significantly inhibit the adsorption of extracellular polymeric substances (EPS) which dominates fouling propensity, resulting in the formation of a thin biofilm with high porosity under synthetic functions of foulants deposition and microbial activities. Interfacial free energy prediction affirmed the presence of zwitterionic functional layer on membrane surface could substantially decrease the interactions (e.g., electrostatic attractions and hydrophobic effects) between membrane and foulants, thereby reduced flux decline and high stable flux. Our study suggests surface hydrophilic functionalization shows promising potential for improving the performance of ultra-low pressure filtration. (C) 2019 Elsevier Ltd. All rights reserved. |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/45259]  |
| 专题 | 生态环境研究中心_中国科学院饮用水科学与技术重点实验室 |
| 推荐引用方式 GB/T 7714 | Liu, Caihong,Song, Dan,Zhang, Wenjuan,et al. Constructing zwitterionic polymer brush layer to enhance gravity-driven membrane performance by governing biofilm formation[J]. WATER RESEARCH,2020,168:1-26. |
| APA | Liu, Caihong.,Song, Dan.,Zhang, Wenjuan.,He, Qiang.,Huangfu, Xiaoliu.,...&Ma, Jun.(2020).Constructing zwitterionic polymer brush layer to enhance gravity-driven membrane performance by governing biofilm formation.WATER RESEARCH,168,1-26. |
| MLA | Liu, Caihong,et al."Constructing zwitterionic polymer brush layer to enhance gravity-driven membrane performance by governing biofilm formation".WATER RESEARCH 168(2020):1-26. |
入库方式： OAI收割
来源：生态环境研究中心
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。