Site-Fixed Hydroboration of Terminal and Internal Alkenes using BX3/iPr2NEt
文献类型：期刊论文
| 作者 | Li SD(李思达)2; Hu CY(胡晨阳)1; Cui X(崔鑫)2; Zhang J(张炯)2; Liu L(刘柳)1; Wu LP(吴立朋)2
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| 刊名 | Angew. Chem., Int. Ed.
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| 出版日期 | 2021-11 |
| 期号 | 未出页码:未出 |
| DOI | 10.1002/anie.202111978 |
| 英文摘要 | A novel and general method for the hydroboration of alkenes, including aryl alkenes, 1,1-disubstituted alkenes, aliphatic alkenes, and bio-derived alkenes, using BX3 as the boration reagent in the presence of iPr2NEt is reported. The reaction was also applied to the synthesis of linear and branched 1,n-diborylalkanes. The reaction is thought to proceed by a frustrated Lewis pair type single-electron-transfer mechanism. |
| URL标识 | 查看原文 |
| 语种 | 英语 |
| 源URL | [http://ir.licp.cn/handle/362003/27553]  |
| 专题 | 中国科学院兰州化学物理研究所 |
| 通讯作者 | Liu L(刘柳); Wu LP(吴立朋) |
| 作者单位 | 1.南方科技大学 2.中国科学院兰州化学物理研究所 |
| 推荐引用方式 GB/T 7714 | Li SD,Hu CY,Cui X,et al. Site-Fixed Hydroboration of Terminal and Internal Alkenes using BX3/iPr2NEt[J]. Angew. Chem., Int. Ed.,2021(未出):未出. |
| APA | Li SD,Hu CY,Cui X,Zhang J,Liu L,&Wu LP.(2021).Site-Fixed Hydroboration of Terminal and Internal Alkenes using BX3/iPr2NEt.Angew. Chem., Int. Ed.(未出),未出. |
| MLA | Li SD,et al."Site-Fixed Hydroboration of Terminal and Internal Alkenes using BX3/iPr2NEt".Angew. Chem., Int. Ed. .未出(2021):未出. |
入库方式： OAI收割
来源：兰州化学物理研究所
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