中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis of Allylboronates via Zweifel‐type Deprotonative Olefination

文献类型:期刊论文

作者Xu N(许诺); Xu JN(徐佳能); Zhu Q(朱庆); Liu C(刘超)
刊名Advanced Synthesis & Catalysis
出版日期2020-12
期号363页码:2403-2407
关键词Boron Allylic Compounds Vinylboronates Zweifel Olefination
英文摘要

A method for the synthesis of allylboronates via Zweifel-type deprotonative olefination was demonstrated. Tetrasubstituted vinylboronates were used as the substrates. NCS (N-chlorosuccinimide) was used as a bifunctional additive, electrophile and base. This method exhibited a different elimination strategy in Zweifel type transformation to afford allylboronates. The homo-alcohols and alkenes were stereoselective synthesized from the obtained allylboronates, demonstrating the synthetic value of this methodology.

源URL[http://ir.licp.cn/handle/362003/27485]  
专题兰州化学物理研究所_OSSO国家重点实验室
通讯作者Xu N(许诺)
推荐引用方式
GB/T 7714
Xu N,Xu JN,Zhu Q,et al. Synthesis of Allylboronates via Zweifel‐type Deprotonative Olefination[J]. Advanced Synthesis & Catalysis,2020(363):2403-2407.
APA 许诺,徐佳能,朱庆,&刘超.(2020).Synthesis of Allylboronates via Zweifel‐type Deprotonative Olefination.Advanced Synthesis & Catalysis(363),2403-2407.
MLA 许诺,et al."Synthesis of Allylboronates via Zweifel‐type Deprotonative Olefination".Advanced Synthesis & Catalysis .363(2020):2403-2407.

入库方式: OAI收割

来源:兰州化学物理研究所

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