An oxidation-nitridation-denitridation approach to transform metal solids into foams with adjustable pore sizes for energy applications
文献类型:期刊论文
作者 | Qin, Hao1,2; Zhen, Chao1; Jia, Chunxu1,2; Yang, Zhiqing1; Ye, Hengqiang1; Cheng, Hui-Ming1,3; Liu, Gang1,2 |
刊名 | SCIENCE BULLETIN
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出版日期 | 2021-08-15 |
卷号 | 66期号:15页码:1525-1532 |
关键词 | Metal foams Hierarchically porous structures Electrocatalytic water splitting Supercapacitor |
ISSN号 | 2095-9273 |
DOI | 10.1016/j.scib.2021.04.031 |
通讯作者 | Liu, Gang(gangliu@imr.ac.cn) |
英文摘要 | Metal foams with hierarchically porous structures are highly desirable in energy applications as active materials or their host substrates. However, conventional preparation methods usually have a quite limited flexibility of adjusting pore size of metal foams. Herein, an alternative new method based on gaseous thermal oxidation-nitridation-denitridation processes was developed to prepare metal (copper and nickel) foams with adjustable pore size by controlling the thermal nitridation temperature. Moreover, this environment-friendly method is independent of the shape of starting pure metal substrates and can be repeatedly applied to the metal substrates to create hierarchical porous structures containing different size pores. As a demonstration of the advantages of the resultant foams with abundant pores by this method, compared with its starting material (commercial Ni foam with the pore size of several millimeters), the resultant hierarchical porous Ni foam gives the remarkably enhanced performance of electrochemical water splitting as HER/OER electrodes and electrochemical energy storage as the host substrate of capacitive material MnO2. The metal foams with adjustable pore size prepared by the developed method will find a wide range of important applications in energy storage and conversion areas. (c) 2021 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved. |
资助项目 | National Natural Science Foundation of China[51825204] ; Key Research Program of Frontier Sciences CAS[QYZDB-SSW-JSC039] |
WOS研究方向 | Science & Technology - Other Topics |
语种 | 英语 |
WOS记录号 | WOS:000684396500010 |
出版者 | ELSEVIER |
资助机构 | National Natural Science Foundation of China ; Key Research Program of Frontier Sciences CAS |
源URL | [http://ir.imr.ac.cn/handle/321006/159245] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Liu, Gang |
作者单位 | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 3.Tsinghua Univ, Tsinghua Berkeley Shenzhen Inst, Low Dimens Mat & Device Lab, Shenzhen 518055, Peoples R China |
推荐引用方式 GB/T 7714 | Qin, Hao,Zhen, Chao,Jia, Chunxu,et al. An oxidation-nitridation-denitridation approach to transform metal solids into foams with adjustable pore sizes for energy applications[J]. SCIENCE BULLETIN,2021,66(15):1525-1532. |
APA | Qin, Hao.,Zhen, Chao.,Jia, Chunxu.,Yang, Zhiqing.,Ye, Hengqiang.,...&Liu, Gang.(2021).An oxidation-nitridation-denitridation approach to transform metal solids into foams with adjustable pore sizes for energy applications.SCIENCE BULLETIN,66(15),1525-1532. |
MLA | Qin, Hao,et al."An oxidation-nitridation-denitridation approach to transform metal solids into foams with adjustable pore sizes for energy applications".SCIENCE BULLETIN 66.15(2021):1525-1532. |
入库方式: OAI收割
来源:金属研究所
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